A review of plutonium oxalate decomposition reactions and effects of decomposition temperature on the surface area of the plutonium dioxide product

RM Orr, HE Sims, RJ Taylor - Journal of Nuclear Materials, 2015 - Elsevier
Abstract Plutonium (IV) and (III) ions in nitric acid solution readily form insoluble precipitates
with oxalic acid. The plutonium oxalates are then easily thermally decomposed to form …

Aliovalent doping of CeO 2: DFT study of oxidation state and vacancy effects

DEP Vanpoucke, P Bultinck, S Cottenier… - Journal of Materials …, 2014 - pubs.rsc.org
The modification of CeO2 properties by means of aliovalent doping is investigated within the
ab initio density functional theory framework. Lattice parameters, dopant atomic radii, bulk …

Role of Microstructure and Surface Defects on the Dissolution Kinetics of CeO2, a UO2 Fuel Analogue

CL Corkhill, DJ Bailey, FY Tocino… - … applied materials & …, 2016 - ACS Publications
The release of radionuclides from spent fuel in a geological disposal facility is controlled by
the surface mediated dissolution of UO2 in groundwater. In this study we investigate the …

Probing the local structure of nanoscale actinide oxides: a comparison between PuO 2 and ThO 2 nanoparticles rules out PuO 2+ x hypothesis

L Bonato, M Virot, T Dumas, A Mesbah… - Nanoscale …, 2020 - pubs.rsc.org
Actinide research at the nanoscale is gaining fundamental interest due to environmental and
industrial issues. The knowledge of the local structure and speciation of actinide …

Coordination-enhanced extraction of rare earth metals from waste polishing powder and facile preparation of a mesoporous Ce-La oxide

X He, L Chen, P Chen, W Liu, D Zhang… - Chemical Engineering …, 2023 - Elsevier
Efficient and environmental-friendly recycling of rare earth polishing powder waste (REPPW)
is imperative not only to ecological well-being but also to sustainability of critical rare earth …

Dissolution of nuclear materials in aqueous acid solutions

N Desigan, N Bhatt, MA Shetty… - Reviews in Chemical …, 2019 - degruyter.com
The quantitative understanding of the dissolution of nuclear fuel materials is essential for the
process design and development of an industrial-scale nuclear fuel reprocessing plant. The …

Monazite transformation into Ce‐ and La‐containing oxalates by Aspergillus niger

X Kang, L Csetenyi, GM Gadd - Environmental microbiology, 2020 - Wiley Online Library
Monazite is a naturally occurring lanthanide (Ln) phosphate mineral [Ln x (PO4) y] and is the
main industrial source of the rare earth elements (REE), cerium and lanthanum. Endeavours …

Phosphate Ca1/4Sr1/4Zr2 (PO4) 3 of the NaZr2 (PO4) 3 structure type: Synthesis of a dense ceramic material and its radiation testing

AI Orlova, VY Volgutov, DA Mikhailov, DM Bykov… - Journal of nuclear …, 2014 - Elsevier
The powder of phosphate Ca 1/4 Sr 1/4 Zr 2 (PO 4) 3 was synthesized by sol–gel processes
in the presence of citric acid and ethylene glycol. Ceramic samples were prepared from this …

Multiparametric dissolution of thorium–cerium dioxide solid solutions

L Claparede, N Clavier, N Dacheux, A Mesbah… - Inorganic …, 2011 - ACS Publications
The dissolution of Th1–x Ce x O2 solid solutions samples prepared by thermal conversion of
oxalate precursors was studied by varying independently several parameters (such as …

Environmental SEM monitoring of Ce 1− x Ln x O 2− x/2 mixed-oxide microstructural evolution during dissolution

D Horlait, L Claparede, F Tocino, N Clavier… - Journal of Materials …, 2014 - pubs.rsc.org
The microstructural evolution of several Ce1− xLnxO2− x/2 (Ln= Nd, Er, x= 0.28; 0.59 and
0.76) sintered pellets was studied during their dissolution in 4 M HNO3 at 90° C or 60° C …