A review of plutonium oxalate decomposition reactions and effects of decomposition temperature on the surface area of the plutonium dioxide product
RM Orr, HE Sims, RJ Taylor - Journal of Nuclear Materials, 2015 - Elsevier
Abstract Plutonium (IV) and (III) ions in nitric acid solution readily form insoluble precipitates
with oxalic acid. The plutonium oxalates are then easily thermally decomposed to form …
with oxalic acid. The plutonium oxalates are then easily thermally decomposed to form …
Aliovalent doping of CeO 2: DFT study of oxidation state and vacancy effects
The modification of CeO2 properties by means of aliovalent doping is investigated within the
ab initio density functional theory framework. Lattice parameters, dopant atomic radii, bulk …
ab initio density functional theory framework. Lattice parameters, dopant atomic radii, bulk …
Role of Microstructure and Surface Defects on the Dissolution Kinetics of CeO2, a UO2 Fuel Analogue
The release of radionuclides from spent fuel in a geological disposal facility is controlled by
the surface mediated dissolution of UO2 in groundwater. In this study we investigate the …
the surface mediated dissolution of UO2 in groundwater. In this study we investigate the …
Probing the local structure of nanoscale actinide oxides: a comparison between PuO 2 and ThO 2 nanoparticles rules out PuO 2+ x hypothesis
Actinide research at the nanoscale is gaining fundamental interest due to environmental and
industrial issues. The knowledge of the local structure and speciation of actinide …
industrial issues. The knowledge of the local structure and speciation of actinide …
Coordination-enhanced extraction of rare earth metals from waste polishing powder and facile preparation of a mesoporous Ce-La oxide
X He, L Chen, P Chen, W Liu, D Zhang… - Chemical Engineering …, 2023 - Elsevier
Efficient and environmental-friendly recycling of rare earth polishing powder waste (REPPW)
is imperative not only to ecological well-being but also to sustainability of critical rare earth …
is imperative not only to ecological well-being but also to sustainability of critical rare earth …
Dissolution of nuclear materials in aqueous acid solutions
N Desigan, N Bhatt, MA Shetty… - Reviews in Chemical …, 2019 - degruyter.com
The quantitative understanding of the dissolution of nuclear fuel materials is essential for the
process design and development of an industrial-scale nuclear fuel reprocessing plant. The …
process design and development of an industrial-scale nuclear fuel reprocessing plant. The …
Monazite transformation into Ce‐ and La‐containing oxalates by Aspergillus niger
Monazite is a naturally occurring lanthanide (Ln) phosphate mineral [Ln x (PO4) y] and is the
main industrial source of the rare earth elements (REE), cerium and lanthanum. Endeavours …
main industrial source of the rare earth elements (REE), cerium and lanthanum. Endeavours …
Phosphate Ca1/4Sr1/4Zr2 (PO4) 3 of the NaZr2 (PO4) 3 structure type: Synthesis of a dense ceramic material and its radiation testing
AI Orlova, VY Volgutov, DA Mikhailov, DM Bykov… - Journal of nuclear …, 2014 - Elsevier
The powder of phosphate Ca 1/4 Sr 1/4 Zr 2 (PO 4) 3 was synthesized by sol–gel processes
in the presence of citric acid and ethylene glycol. Ceramic samples were prepared from this …
in the presence of citric acid and ethylene glycol. Ceramic samples were prepared from this …
Multiparametric dissolution of thorium–cerium dioxide solid solutions
The dissolution of Th1–x Ce x O2 solid solutions samples prepared by thermal conversion of
oxalate precursors was studied by varying independently several parameters (such as …
oxalate precursors was studied by varying independently several parameters (such as …
Environmental SEM monitoring of Ce 1− x Ln x O 2− x/2 mixed-oxide microstructural evolution during dissolution
The microstructural evolution of several Ce1− xLnxO2− x/2 (Ln= Nd, Er, x= 0.28; 0.59 and
0.76) sintered pellets was studied during their dissolution in 4 M HNO3 at 90° C or 60° C …
0.76) sintered pellets was studied during their dissolution in 4 M HNO3 at 90° C or 60° C …