The Kabachnik–Fields reaction: Mechanism and synthetic use
G Keglevich, E Bálint - Molecules, 2012 - mdpi.com
The Kabachnik–Fields (phospha-Mannich) reaction involving the condensation of primary or
secondary amines, oxo compounds (aldehydes and ketones) and> P (O) H species …
secondary amines, oxo compounds (aldehydes and ketones) and> P (O) H species …
Synthesis of α-aminophosphonates and related derivatives; The last decade of the Kabachnik–Fields reaction
PR Varga, G Keglevich - Molecules, 2021 - mdpi.com
The Kabachnik–Fields reaction, comprising the condensation of an amine, oxo compound
and a P-reagent (generally a> P (O) H species or trialkyl phosphite), still attracts interest due …
and a P-reagent (generally a> P (O) H species or trialkyl phosphite), still attracts interest due …
Visible‐Light‐Driven Selective Oxidative Coupling of Amines to Imines by Bismuth‐Rich Bismuth Oxybromide in Water
W Zhao, C Yang, X Zhang, Y Deng, C Han… - …, 2020 - Wiley Online Library
Photocatalytic selective oxidative coupling of amines is a promising method for imine
synthesis. Bismuth‐rich bismuth oxybromide photocatalysts have been found to exhibit …
synthesis. Bismuth‐rich bismuth oxybromide photocatalysts have been found to exhibit …
New N-acyl-as well as N-phosphonoylmethyl-and N-phosphinoylmethyl-α-amino-benzylphosphonates by acylation and a tandem Kabachnik–Fields protocol
Diethyl α-benzylamino-and α-amino-benzylphosphonates obtained by the Kabachnik–
Fields reaction were useful intermediates in the synthesis of other derivatives. Acylation of α …
Fields reaction were useful intermediates in the synthesis of other derivatives. Acylation of α …
N-Benzyl and N-aryl bis (phospha-Mannich adducts): Synthesis and catalytic activity of the related bidentate chelate platinum complexes in hydroformylation
The microwave-assisted double Kabachnik–Fields (phospha-Mannich) reaction of
benzylamine and arylamines, two equivalents of paraformaldehyde and the P (O) H reagent …
benzylamine and arylamines, two equivalents of paraformaldehyde and the P (O) H reagent …
Phospha-Mannich reactions of PH3 and its analogs
DV Moiseev, BR James - Phosphorus, Sulfur, and Silicon and the …, 2022 - Taylor & Francis
The easiest route to form compounds with P–C sp3–N linkage (s) is phosphorus-based
Mannich-type reactions (phospha-Mannich reactions) between phosphines (R3P, R2PH …
Mannich-type reactions (phospha-Mannich reactions) between phosphines (R3P, R2PH …
A neighbouring group effect leading to enhanced nucleophilic substitution of amines at the hindered α-carbon atom of an α-hydroxyphosphonate
Diethyl α-hydroxy-benzylphosphonate undergoes nucleophilic substitution with primary
amines of sufficient reactivity at around 100° C to afford the corresponding α …
amines of sufficient reactivity at around 100° C to afford the corresponding α …
Feedback control of oximation reaction by inline Raman spectroscopy
Although the process analytical technology for ensuring constant product quality and tight
control over the manufacturing process, which is especially important in the case of …
control over the manufacturing process, which is especially important in the case of …
The Synthesis of N,N‐Bis(dialkoxyphosphinoylmethyl)‐ and N,N‐Bis(diphenylphosphinoylmethyl)glycine Esters by the Microwave‐Assisted Double Kabachnik …
The condensation of a glycine ester, two equivalents of paraformaldehyde, and the same
quantity of a dialkyl phosphite or diphenylphosphine oxide afforded the title compounds as …
quantity of a dialkyl phosphite or diphenylphosphine oxide afforded the title compounds as …
Asymmetric Electrophilic Reactions in Phosphorus Chemistry
AO Kolodiazhna, OI Kolodiazhnyi - Symmetry, 2020 - mdpi.com
This review is devoted to the theoretic and synthetic aspects of asymmetric electrophilic
substitution reactions at the stereogenic phosphorus center. The stereochemistry and …
substitution reactions at the stereogenic phosphorus center. The stereochemistry and …