Spectroscopic techniques to probe magnetic anisotropy and spin–phonon coupling in metal complexes
AT Hand, BD Watson-Sanders, ZL Xue - Dalton Transactions, 2024 - pubs.rsc.org
Magnetism of molecular quantum materials such as single-molecule magnets (SMMs) has
been actively studied for potential applications in the new generation of high-density data …
been actively studied for potential applications in the new generation of high-density data …
Single-ion anisotropy and exchange coupling in cobalt (II)-radical complexes: insights from magnetic and ab initio studies
GK Gransbury, ME Boulon, RA Mole, RW Gable… - Chemical …, 2019 - pubs.rsc.org
The concurrent effects of single-ion anisotropy and exchange interactions on the electronic
structure and magnetization dynamics have been analyzed for a cobalt (II)-semiquinonate …
structure and magnetization dynamics have been analyzed for a cobalt (II)-semiquinonate …
Redox Ladder of Ni3 Complexes with Closed‐Shell, Mono‐, and Diradical Triphenylene Units: Molecular Models for Conductive 2D MOFs
We report the isolation and characterization of a series of trinickel complexes with 2, 3, 6, 7,
10, 11‐hexaoxytriphenylene (HOTP),[(Me3TPANi) 3 (HOTP)](BF4) n (Me3TPA= N, N, N‐tris …
10, 11‐hexaoxytriphenylene (HOTP),[(Me3TPANi) 3 (HOTP)](BF4) n (Me3TPA= N, N, N‐tris …
Dynamic Magnetic Susceptibility Method in Studies of Coordination Compounds
NN Efimov, KA Babeshkin, AV Rotov - Russian Journal of Coordination …, 2024 - Springer
The measurement of the dynamic magnetic susceptibility is a universal method, which is
used for the evaluation of magnetic properties of single molecule magnets by scientists all …
used for the evaluation of magnetic properties of single molecule magnets by scientists all …
Purely spectroscopic determination of the spin Hamiltonian parameters in high-spin six-coordinated cobalt (II) complexes with large zero-field splitting
EY Misochko, AV Akimov, DV Korchagin… - Inorganic …, 2019 - ACS Publications
Accurate determination of the spin Hamiltonian parameters in transition-metal complexes
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …
Field-induced slow magnetic relaxation in pseudooctahedral cobalt (II) complexes with positive axial and large rhombic anisotropy
The preparation, X-ray crystal structure, spectroscopic and variable-temperature dc and ac
magnetic properties of two six-coordinate cobalt (II) complexes of formula [Co (bim) 4 (tcm) …
magnetic properties of two six-coordinate cobalt (II) complexes of formula [Co (bim) 4 (tcm) …
Magnetic interactions controlled by light in the family of Fe (II)–M (IV)(M= Mo, W, Nb) hybrid organic–inorganic frameworks
M Magott, M Ceglarska, M Rams, B Sieklucka… - Dalton …, 2022 - pubs.rsc.org
Three new hybrid organic–inorganic frameworks employing octacyanidometallates and 4,
4′-bypiridine dioxide (4, 4′-bpdo) as bridging molecules were prepared and …
4′-bypiridine dioxide (4, 4′-bpdo) as bridging molecules were prepared and …
Synthesis, structure, and characterisation of a ferromagnetically coupled dinuclear complex containing Co (ii) ions in a high spin configuration and thiodiacetate and …
AL Pérez, A Kemmerer, AJ Zapata, R Sartoris… - Dalton …, 2023 - pubs.rsc.org
We report the synthesis, crystal structure, and characterisation of a dinuclear Co (II)
compound with thiodiacetate (tda) and phenanthroline (phen) as ligands (1), and of a series …
compound with thiodiacetate (tda) and phenanthroline (phen) as ligands (1), and of a series …
Zero-field splitting calculations by multiconfiguration pair-density functional theory
Zero-field splitting (ZFS) is a fundamental molecular property that is especially relevant for
single-molecule magnets (SMMs), electron paramagnetic resonance spectra, and quantum …
single-molecule magnets (SMMs), electron paramagnetic resonance spectra, and quantum …
Guest-induced pore breathing controls the spin state in a cyanido-bridged framework
Iron (II) spin cross-over (SCO) compounds combine a thermally driven transition from the
diamagnetic low-spin (LS) state to the paramagnetic high-spin (HS) state with a distinct …
diamagnetic low-spin (LS) state to the paramagnetic high-spin (HS) state with a distinct …