Conspectus Noncovalent interactions are ubiquitous in organic systems, and can play
decisive roles in the outcome of asymmetric organocatalytic reactions. Their prevalence …

The addition of an organometallic reagent to a carbonyl compound or an imine represents
an important process in synthetic organic chemistry because in this reaction, together with a …

Conjugate addition is among the most important synthetic protocols for constructing carbon
skeletons and is widely used to synthesize natural products and drugs. However …

Rhodium (I)-catalyzed atroposelective C–H arylation of heterobiaryls was presented. In the
presence of a Rh catalyst derived from [Rh (C2H4) 2Cl] 2 and a TADDOL-derived …

Herein, a protocol for enantioconvergent transformation of anisole derivatives is disclosed
via nickel-catalyzed dynamic kinetic asymmetric cross-coupling of the C (Ar)–OMe bond …

An atroposelectively diversity-oriented synthetic strategy was developed for the divergent
synthesis of axially chiral heterocycles through organocatalytic asymmetric intramolecular …

Herein, we report a cobalt-catalyzed atroposelective reductive cross-coupling of racemic
heterobiaryl tosylates with a C (sp2)–X type electrophile. Both aryl and alkenyl halides are …

An efficient protocol to synthesize axially chiral compounds via kinetic resolution by Pd (II)-
catalyzed direct C–H iodination was realized (up to s= 27). The iodide product could be …

The catalytic hydroarylation of alkynes has emerged as an excellent methodology for the
synthesis of functionalized alkenes with excellent levels of regio-and stereocontrol (syn) …

Herein, we describe the feasibility of atroposelective PIII/PV= O redox organocatalysis by the
Staudinger–aza‐Wittig reaction. The formation of isoquinoline heterocycles thereby enables …