This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

The demand for more efficient ways to construct complex chemical structures from simple,
readily available precursors continues unabated. A very attractive way to meet this demand …

Chiral phosphinooxazolines (PHOX ligands), which coordinate to a metal center with a N-
and a P-atom, allow effective enantiocontrol in a variety of metal-catalyzed reactions. They …

Proteinogenic and non-proteinogenic R-amino acids (R-AAs) constitute one of the five most
important families of natural products1 and are essential molecules in many scientific areas …

Catalytic asymmetric CC bond-forming reactions using organometallic reagents are among
the most important of organic transformations. 1 Frequently, these transformations are key …

Recent trends in the pharmaceutical industry demonstrate that the number of new chemical
entities (NCEs) launched on the market each year has been steadily declining over the last …

A nuclearity‐dependent enantiodivergent epoxide opening reaction has been developed, in
which both antipodes of chiral alcohol products are selectively accessed by mononuclear …

The Enantioselective Tsuji Allylation | Journal of the American Chemical Society ACS ACS
Publications C&EN CAS Find my institution Log In Journal of the American Chemical Society …

Discovering efficient methods for gaining access to enantiomerically pure compounds in the
development of pharmaceuticals, agrochemicals, and flavors has been a great challenge for …

All‐carbon quaternary stereocenters have posed significant challenges in the synthesis of
complex natural products. These important structural motifs have inspired the development …