Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Transition-metal-catalyzed nucleophilic addition of organometallic reagents to polar
unsaturated substrates is one of the most important and powerful bond-forming strategies …

Metal‐catalyzed reductive coupling reactions of aryl halides and (pseudo) halides with
carbonyl‐type compounds have undergone an impressive development within the last …

Chiral molecules containing asymmetric carbon centers bonded with nitrogen are ubiquitous
in nature and also form important structural fragments in both natural and man-made …

A new coupling protocol has been developed that allows the union of vinyl sulfones with
photoredox-generated α-amino radicals to provide allylic amines of broad diversity. Direct C …

The addition of an organometallic reagent to a carbonyl compound or an imine represents
an important process in synthetic organic chemistry because in this reaction, together with a …

The review examines the chiral amine literature from 2000–2009 (May) concerning
enantioselective and diastereoselective methods for N‐acylenamide and enamine …

Enantioenriched alcohols found in an array of bioactive natural products and
pharmaceutical agents are often synthesized by asymmetric nucleophilic addition to …

A Co-catalyzed highly regio-and enantioselective reductive coupling of alkynes and
aldehydes has been developed under visible light photoredox dual catalysis. A variety of …

Chiral tertiary alcohols are an important class of organic compounds which have found wide
applications in both academia and industry. Therefore, various synthetic strategies towards …