Group 16 conjugated polymers based on furan, thiophene, selenophene, and tellurophene

S Ye, V Lotocki, H Xu, DS Seferos - Chemical Society Reviews, 2022 - pubs.rsc.org
Five-membered aromatic rings containing Group 16 elements (O, S, Se, and Te), also
referred as chalcogenophenes, are ubiquitous building blocks for π-conjugated polymers …

Recent advances in homogeneous nickel catalysis

SZ Tasker, EA Standley, TF Jamison - Nature, 2014 - nature.com
Tremendous advances have been made in nickel catalysis over the past decade. Several
key properties of nickel, such as facile oxidative addition and ready access to multiple …

Nickel-catalyzed cross-couplings involving carbon− oxygen bonds

BM Rosen, KW Quasdorf, DA Wilson, N Zhang… - Chemical …, 2011 - ACS Publications
REVIEW intricate molecular topologies and architectures. To turn the molecular dreams into
a reality, synthetic chemists must ultimately roll up their sleeves and become molecular …

Miniaturization of NMR systems: Desktop spectrometers, microcoil spectroscopy, and “NMR on a chip” for chemistry, biochemistry, and industry

SS Zalesskiy, E Danieli, B Blumich… - Chemical …, 2014 - ACS Publications
Nuclear magnetic resonance spectroscopy (NMR) nowadays is one of the most powerful
and versatile analytical methods for modern organic chemistry,(1) catalysis,(2) biology,(3) …

A broadly applicable strategy for entry into homogeneous nickel (0) catalysts from air-stable nickel (II) complexes

EA Standley, SJ Smith, P Müller, TF Jamison - Organometallics, 2014 - ACS Publications
A series of air-stable nickel complexes of the form L2Ni (aryl) X (L= monodentate phosphine,
X= Cl, Br) and LNi (aryl) X (L= bis-phosphine) have been synthesized and are presented as …

Poly (3-hexylthiophene): synthetic methodologies and properties in bulk heterojunction solar cells

A Marrocchi, D Lanari, A Facchetti… - Energy & Environmental …, 2012 - pubs.rsc.org
Poly (3-hexylthiophene)(P3HT) remains of significant importance as a prototypical
benchmark hole conductor material in Organic Photovoltaics (OPVs). In this review we …

Improving the Halogen–Magnesium Exchange by using New Turbo‐Grignard Reagents

DS Ziegler, B Wei, P Knochel - Chemistry–A European Journal, 2019 - Wiley Online Library
This Minireview describes the scope of the halogen–magnesium exchange. It shows that the
use of the turbo‐Grignard reagent (iPrMgCl⋅ LiCl) greatly enhances the rate of the Br–and I …

Kumada Catalyst‐Transfer Polycondensation: Mechanism, Opportunities, and Challenges

A Kiriy, V Senkovskyy, M Sommer - Macromolecular rapid …, 2011 - Wiley Online Library
Kumada catalyst‐transfer polycondensation (KCTP) is a new but rapidly developing method
with great potential for the preparation of well‐defined conjugated polymers (CPs). The …

Progress and developments in the turbo Grignard reagent i-PrMgClĚLiCl: a ten-year journey

RLY Bao - Chemical Communications, 2015 - pubs.rsc.org
Over the past decade, the effectiveness of i-PrMgCl· LiCl has been constantly highlighted by
a number of research groups. Its enhanced nucleophilicity brings prosperity to highly …

Conjugated polymer synthesis via catalyst-transfer polycondensation (CTP): mechanism, scope, and applications

ZJ Bryan, AJ McNeil - Macromolecules, 2013 - ACS Publications
The recent discovery of a living, controlled chain-growth method for synthesizing π-
conjugated polymers has ignited the field and led to the development of many new …