Fluorine has received great attention in all fields of science.“Small atom with a big ego” was
the title of the Symposium at the ACS meeting in San Francisco in 2000, where a number of …

Thieme E-Journals - Synthesis / Full Text DE EN Home Products Journals Books Book Series
Service Library Service Help Contact Portal SYNTHESIS Full-text search Full-text search Author …

Partially fluorinated alkyl groups other than methyl are increasingly playing crucial roles in
the development of fluorinated drugs with diverse biological activities, thus creating an …

Preparations, reactions, and synthetic applications of functionalized fluoroalkyl and alkenyl
silanes have been summarized. This review focuses mainly on the chemistries of (1) 1 …

(E)-Trimethyl-(3, 3, 3-trifluoroprop-1-enyl) silane (1) was synthesized as a reagent for use in
Hiyama cross-coupling reactions for the production of β-trifluoromethylstyrene derivatives …

The first anionic pentacoordinated group 14 compounds bearing a phenylethynyl substituent
were successfully synthesized and crystallographically characterized. The synthesized ate …

The first representatives of an unknown family of organoboron compounds, the
((perfluoroorgano) ethynyl) trifluoroborate salts K [RFC⋮ CBF3](RF= CF3, C3F7,(CF3) 2CF …

Tributyl (3, 3, 3-trifluoro-1-propynyl) stannane was readily synthesized from 2-bromo-3, 3, 3-
trifluoropropene in one step. The 1, 3-dipolar cycloaddition of the stannane with …

The reaction of (trifluoromethyl) dimethylphenylsilylacetylene and (η2-propene) Ti (O i Pr) 2
generated in situ smoothly proceeded giving the corresponding (η2-1-dimethylphenylsilyl-2 …

The reaction of the rhodium (I) complexes [Rh (E)(PEt3) 3](E= GePh3 (1), Si (OEt) 3 (5)) with
HFO-1234yf (2, 3, 3, 3-tetrafluoropropene) afforded [Rh (F)(PEt3) 3](2) and the …