Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …
and selectivity. However, the structural complexity and vulnerability hamper the application …
Oxygen activation and radical transformations in heme proteins and metalloporphyrins
As a result of the adaptation of life to an aerobic environment, nature has evolved a panoply
of metalloproteins for oxidative metabolism and protection against reactive oxygen species …
of metalloproteins for oxidative metabolism and protection against reactive oxygen species …
Characterization and heterologous reconstitution of Taxus biosynthetic enzymes leading to baccatin III
B Jiang, L Gao, H Wang, Y Sun, X Zhang, H Ke, S Liu… - Science, 2024 - science.org
Paclitaxel is a well known anticancer compound. Its biosynthesis involves the formation of a
highly functionalized diterpenoid core skeleton (baccatin III) and the subsequent assembly …
highly functionalized diterpenoid core skeleton (baccatin III) and the subsequent assembly …
A general strategy for decoupled hydrogen production from water splitting by integrating oxidative biomass valorization
Conventional water electrolyzers produce H2 and O2 simultaneously, such that additional
gas separation steps are needed to prevent H2/O2 mixing. The sluggish anodic O2 …
gas separation steps are needed to prevent H2/O2 mixing. The sluggish anodic O2 …
Mechanisms of cytochrome P450-catalyzed oxidations
FP Guengerich - ACS catalysis, 2018 - ACS Publications
Enzymes are complex biological catalysts and are critical to life. Most oxidations of
chemicals are catalyzed by cytochrome P450 (P450, CYP) enzymes, which generally utilize …
chemicals are catalyzed by cytochrome P450 (P450, CYP) enzymes, which generally utilize …
Evolution of C–H bond functionalization from methane to methodology
JF Hartwig - Journal of the American Chemical Society, 2016 - ACS Publications
This Perspective presents the fundamental principles, the elementary reactions, the initial
catalytic systems, and the contemporary catalysts that have converted C–H bond …
catalytic systems, and the contemporary catalysts that have converted C–H bond …
The essential role of bond energetics in C–H activation/functionalization
The most fundamental concepts in chemistry are structure, energetics, reactivity and their
inter-relationships, which are indispensable for promoting chemistry into a rational science …
inter-relationships, which are indispensable for promoting chemistry into a rational science …
Reliably assessing the electronic structure of cytochrome P450 on today's classical computers and tomorrow's quantum computers
An accurate assessment of how quantum computers can be used for chemical simulation,
especially their potential computational advantages, provides important context on how to …
especially their potential computational advantages, provides important context on how to …
Alkane oxidation: methane monooxygenases, related enzymes, and their biomimetics
VCC Wang, S Maji, PPY Chen, HK Lee, SSF Yu… - Chemical …, 2017 - ACS Publications
Methane monooxygenases (MMOs) mediate the facile conversion of methane into methanol
in methanotrophic bacteria with high efficiency under ambient conditions. Because the …
in methanotrophic bacteria with high efficiency under ambient conditions. Because the …
[PDF][PDF] Zirconium‐metalloporphyrin PCN‐222: mesoporous metal–organic frameworks with ultrahigh stability as biomimetic catalysts
Methyl 4-formylbenzoate was purchased from Oakwood Products. Inc. Pyrrole, propionic
acid, N, N-dimethylformamide (DMF), N, N-diethylformamide (DEF), benzoic acid, acetone …
acid, N, N-dimethylformamide (DMF), N, N-diethylformamide (DEF), benzoic acid, acetone …