Photocatalytic late-stage C–H functionalization

P Bellotti, HM Huang, T Faber, F Glorius - Chemical Reviews, 2023 - ACS Publications
The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

Green chemistry in the synthesis of pharmaceuticals

S Kar, H Sanderson, K Roy, E Benfenati… - Chemical …, 2021 - ACS Publications
The principles of green chemistry (GC) can be comprehensively implemented in green
synthesis of pharmaceuticals by choosing no solvents or green solvents (preferably water) …

Rational design of photocatalysts for controlled polymerization: effect of structures on photocatalytic activities

C Wu, N Corrigan, CH Lim, W Liu, G Miyake… - Chemical …, 2022 - ACS Publications
Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …

CO2-mediated organocatalytic chlorine evolution under industrial conditions

J Yang, WH Li, HT Tang, YM Pan, D Wang, Y Li - Nature, 2023 - nature.com
During the chlor-alkali process, in operation since the nineteenth century, electrolysis of
sodium chloride solutions generates chlorine and sodium hydroxide that are both important …

Synthetic methods driven by the photoactivity of electron donor–acceptor complexes

GEM Crisenza, D Mazzarella… - Journal of the American …, 2020 - ACS Publications
The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …

Enlightening dynamic functions in molecular systems by intrinsically chiral light-driven molecular motors

J Sheng, DRS Pooler, BL Feringa - Chemical Society Reviews, 2023 - pubs.rsc.org
Chirality is a fundamental property which plays a major role in chemistry, physics, biological
systems and materials science. Chiroptical artificial molecular motors (AMMs) are a class of …

Alkyl borane-mediated metal-free ring-opening (co) polymerizations of oxygenated monomers

C Zhang, X Geng, X Zhang, Y Gnanou… - Progress in Polymer …, 2023 - Elsevier
Sensibility to environmental concerns and the actual demand for polymeric materials free of
any metal contaminants in most applications have directed research towards significant …

Power of biocatalysis for organic synthesis

CK Winkler, JH Schrittwieser, W Kroutil - ACS central science, 2021 - ACS Publications
Biocatalysis, using defined enzymes for organic transformations, has become a common
tool in organic synthesis, which is also frequently applied in industry. The generally high …

Photoenzymatic enantioselective intermolecular radical hydroamination

Z Zhang, J Feng, C Yang, H Cui, W Harrison, D Zhong… - Nature …, 2023 - nature.com
Since the discovery of Hofmann–Löffler–Freytag reaction more than 130 years ago, both the
structure and reactivity of nitrogen-centred radicals have been widely studied. Nevertheless …

Modern electrochemical aspects for the synthesis of value‐added organic products

S Möhle, M Zirbes, E Rodrigo, T Gieshoff… - Angewandte Chemie …, 2018 - Wiley Online Library
The use of electricity instead of stoichiometric amounts of oxidizers or reducing agents in
synthesis is very appealing for economic and ecological reasons, and represents a major …