Alkylation reactions represent an important organic transformation to form C–C bonds. In
addition to conventional approaches with alkyl halides or sulfonates as alkylating agents …

Hydroaminoalkylation is a powerful, atom-economic catalytic reaction for the reaction of
amines with alkenes and alkynes. This C–H functionalization reaction allows for the atom …

This short review highlights recent catalyst developments from group 3–5 elements reported
in the past few years to promote two highly atom-saving transformations, namely …

Hydroaminoalkylation is a 100% atom economic method for forming Csp3–Csp3 bonds
through C–H activation α to an amine and subsequent reaction with an alkene. When …

Transition metal catalyzed direct Csingle bond H activation followed by functionalization with
unsaturated substrates, such as alkenes and alkynes, is regarded as one of the most …

Primary amine products have been prepared using zirconium-catalyzed
hydroaminoalkylation of alkenes with N-silylated benzylamine substrates. Catalysis using …

The efficient and catalytic amination of unactivated alkenes with simple secondary alkyl
amines is preferentially achieved. A sterically accessible, N, O-chelated cyclic ureate …

Atom‐economic and regioselective C− C bond formation has been achieved by rapid C− H
alkylation of unprotected secondary arylamines with unactivated alkenes. The combination …

Transition‐metal‐catalyzed hydroaminoalkylations of alkenes have made great progress
over the last decade and are heading to become a viable alternative to the industrial …

A series of mono (amidate) Ta and Nb complexes with varying steric and electronic
properties were synthesized. These complexes were screened as precatalysts for the …