Recent developments on the transformation of CO 2 utilising ligand cooperation and related strategies
R Ayyappan, I Abdalghani, RC Da Costa… - Dalton …, 2022 - pubs.rsc.org
A portfolio of value-added chemicals, fuels and building block compounds can be
envisioned from CO2 on an industrial scale. The high kinetic and thermodynamic stabilities …
envisioned from CO2 on an industrial scale. The high kinetic and thermodynamic stabilities …
Cationic Nickel d9‐Metalloradicals [Ni(NHC)2]+
L Tendera, MS Luff, I Krummenacher… - European Journal of …, 2022 - Wiley Online Library
A series of five new homoleptic, linear nickel d9‐complexes of the type [NiI (NHC) 2]+ is
reported. Starting from the literature known Ni (0) complexes [Ni (Mes2Im) 2] 1,[Ni …
reported. Starting from the literature known Ni (0) complexes [Ni (Mes2Im) 2] 1,[Ni …
Three-Electron Nickel (I)/Nickel (0) Half-Bond
NA Dodd, Y Cao, J Bacsa, EC Towles… - Inorganic …, 2022 - ACS Publications
An (N-heterocyclic carbene) nickel (I) cation precursor reacts with the corresponding nickel
(0) complex to form a dinickel (I, 0) monocation. The Ni··· Ni distance in this cation is 0.93 Å …
(0) complex to form a dinickel (I, 0) monocation. The Ni··· Ni distance in this cation is 0.93 Å …
Silyliumylidene Ion Stabilized by Two σ‐Donating Ni (0)‐and Pd (0)‐Fragments
S Takahashi, Y Kazama, N Nakata… - … A European Journal, 2024 - Wiley Online Library
A silyliumylidene ion 2 stabilized by two σ‐donating Ni (0)‐and Pd (0)‐fragments was
successfully synthesized. Due to the σ‐donation of M→ Si interactions, 2 presents a …
successfully synthesized. Due to the σ‐donation of M→ Si interactions, 2 presents a …
Oxidative Addition and β‐Hydride Elimination by a Macrocyclic Dinickel Complex: Observing Bimetallic Elementary Reactions
AR Delaney, AA Kroeger, ML Coote… - … –A European Journal, 2023 - Wiley Online Library
The dinickel (I) complex Ni2 (tBuPONNOPONNO), featuring a planar macrocyclic
diphosphoranide ligand tBuPONNOPONNO, offers a unique architectural platform for …
diphosphoranide ligand tBuPONNOPONNO, offers a unique architectural platform for …
Three-Coordinate Halide and Methyl Complexes of Chromium, Manganese, Iron, Cobalt, and Nickel Enabled by an Imidazolin-2-iminato Ligand
GW Chen, YH Chen, HK Liu, CY Lin - Organometallics, 2023 - ACS Publications
Accessing low-coordinate halide and methyl complexes requires a bulky monodentate or
bidentate ligand. Here, the synthesis and characterization of three-coordinate terminal …
bidentate ligand. Here, the synthesis and characterization of three-coordinate terminal …
Probing Intermediates of Ion/Molecule Reactions by their Independent Gas‐Phase Synthesis and Fragmentation–The Thiomethoxymethyl Complexes [(bipy) M …
G Stebens, B Butschke - Israel Journal of Chemistry, 2023 - Wiley Online Library
In the ion/molecule reaction (IMR) of “rollover”‐cyclometalated [(bipy− H) Pt]+ with (CH3) 2S,
the loss of C2H4 from the encounter complex was observed as the main process some …
the loss of C2H4 from the encounter complex was observed as the main process some …
Cooperative Activation of CO2 and N2O by Heterometallic Complexes Stabilized by N-Heterocyclic Carbenes
Y Lakliang - 2022 - indigo.uic.edu
The motivation to transform gaseous small molecules, CO2 and N2O, into useful chemicals
requires a fundamental understanding of how such molecules can be captured and …
requires a fundamental understanding of how such molecules can be captured and …