Fluorinated polymeric nanoparticles (FPNPs) combine unique properties of fluorocarbon
and polymeric nanoparticles, which has stimulated massive interest for decades. However …

The radical copolymerization of VDF with M monomer, the properties and applications of the
resulting copolymers are presented. First, after listing a non-exhaustive series of …

This Perspective summarizes the features and limitations of reversible addition–
fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and …

Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer
chemistry over the past two decades, thus laying the groundwork for the synthesis of …

This paper provides a third update to the review of reversible deactivation radical
polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC (= S) SR) by a …

In the past 80 years, fluoropolymers have found broad applications in both industrial and
academic settings, owing to their unique physicochemical properties. Copolymerizations of …

This review summarizes recent research on novel photochemical methods for the initiation
and control of the polymerization of main chain fluorinated monomers as exemplified by …

An overview on fluorinated olefin-based architectures prepared by reversible deactivation
radical polymerization (RDRP) techniques and their applications is presented. Controlled …

Conspectus Well-defined fluoropolymers exhibit unique properties such as excellent oil and
water repellency, satisfactory thermal stability, a low refractive index, and low surface …

An unprecedented level of control for the radical polymerization of vinylidene fluoride (VDF),
yielding well‐defined PVDF (at least up to 14 500 g mol− 1) with low dispersity (≤ 1.32) …