The amalgamation of different disciplines is at the heart of reticular chemistry and has
broadened the boundaries of chemistry by opening up an infinite space of chemical …

Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Gases are widely used as energy resources for industry and our daily life. Developing
energy cost efficient porous materials for gas storage and separation is of fundamentally and …

An ideal adsorbent for separation requires optimizing both storage capacity and selectivity,
but maximizing both or achieving a desired balance remain challenging. Herein, a de‐linker …

Gas storage and separation are closely associated with the alleviation of greenhouse effect,
the widespread use of clean energy, the control of toxic gases, and various other aspects in …

Metal-organic frameworks (MOFs) are the most promising porous adsorbents for methane
storage; however, the highest reported storage capacities of about 270 cm 3 (STP) cm− 3 at …

Methane and acetylene represent cleaner fuels, which are considered as ideal alternatives
to fossil fuels. Due to low volumetric energy density at ambient conditions, it is highly …

The separation of gas molecules with similar physicochemical properties is of high
importance but practically entails a substantial energy penalty in chemical industry …

In today's perspective, natural gas has gained considerable attention, due to its low
emission, indigenous availability, and improvement in the extraction technology. Upon …

A proposed low-energy alternative to the separation of alkanes from alkenes by energy-
intensive cryogenic distillation is separation by porous adsorbents. Unfortunately, most …