Hydrogen‐atom tunneling reactions in solid para‐hydrogen and their applications to astrochemistry
H‐atom tunneling reactions play important roles in astrochemistry, but an understanding of
these reactions is still in its infancy. The unique properties associated with quantum solid …
these reactions is still in its infancy. The unique properties associated with quantum solid …
Unique Applications of para-Hydrogen Matrix Isolation to Spectroscopy and Astrochemistry
I Weber, PR Joshi, DT Anderson… - The Journal of Physical …, 2024 - ACS Publications
Cryogenic solid para-hydrogen (p-H2) exhibits pronounced quantum effects, enabling
unique experiments that are typically not possible in noble-gas matrices. The diminished …
unique experiments that are typically not possible in noble-gas matrices. The diminished …
Non-energetic, Low-Temperature Formation of Cα-Glycyl Radical, a Potential Interstellar Precursor of Natural Amino Acids
A Schneiker, S Góbi, PR Joshi, G Bazsó… - The Journal of …, 2021 - ACS Publications
The reaction of H atoms with glycine was investigated at 3.1 K in para-H2, a quantum-solid
host. The reaction was followed by IR spectroscopy, with the spectral analysis aided by …
host. The reaction was followed by IR spectroscopy, with the spectral analysis aided by …
A chemical link between methylamine and methylene imine and implications for interstellar glycine formation
PR Joshi, YP Lee - Communications chemistry, 2022 - nature.com
Methylamine CH3NH2 is considered to be an important precursor of interstellar amino acid
because hydrogen abstraction might lead to the aminomethyl radical• CH2NH2 that can …
because hydrogen abstraction might lead to the aminomethyl radical• CH2NH2 that can …
Identification of HOC•HC(O)H, HOCH2C•O, and HOCH2CH2O• Intermediates in the Reaction of H + Glycolaldehyde in Solid Para-Hydrogen and Its Implication …
PR Joshi, YP Lee - Journal of the American Chemical Society, 2024 - ACS Publications
Glycolaldehyde [HOCH2C (O) H, GA], the primitive sugar-like molecule detected in the
interstellar medium (ISM), is a potential precursor for the synthesis of complex sugars …
interstellar medium (ISM), is a potential precursor for the synthesis of complex sugars …
Successive Hydrogenation of SO and SO2 in Solid para-H2: Formation of Elusive Small Oxoacids of Sulfur
S Gobi, IP Csonka, G Bazso… - ACS Earth and Space …, 2021 - ACS Publications
The small oxoacids of sulfur (SOS), H x SO y (x, y= 1, 2), are considered to be key reactive
intermediates in organic synthesis, biochemical processes, and atmospheric chemistry …
intermediates in organic synthesis, biochemical processes, and atmospheric chemistry …
Potential Catalytic Role of Small Heterocycles in Interstellar H2 Formation: A Laboratory Astrochemistry Study on Furan and Its Hydrogenated Forms
A Schneiker, G Ragupathy, G Bazsó… - The Journal of Physical …, 2022 - ACS Publications
It is now well-accepted in astrochemistry that the formation of interstellar H2 is taking place
on the surface of interstellar grains. It has also been suggested a long time ago that …
on the surface of interstellar grains. It has also been suggested a long time ago that …
Hydrogen-Atom-Assisted Uphill Isomerization of N-Methylformamide in Darkness
N-Methylformamide, HC (O) NH (CH3), is the smallest amide detected in the interstellar
medium that can exist as cis and trans isomers. We performed reactions of H atoms with …
medium that can exist as cis and trans isomers. We performed reactions of H atoms with …
VIZSLA—Versatile ice zigzag sublimation setup for laboratory astrochemistry
In this article, a new multi-functional high-vacuum astrophysical ice setup, VIZSLA (Versatile
Ice Zigzag Sublimation Setup for Laboratory Astrochemistry), is introduced. The instrument …
Ice Zigzag Sublimation Setup for Laboratory Astrochemistry), is introduced. The instrument …
Spectroscopy of molecules confined in solid para-hydrogen
Solid para-hydrogen (pH 2) has emerged as a novel low-temperature matrix host with
unique characteristics associated with a quantum solid. In this chapter, we introduce pH 2 …
unique characteristics associated with a quantum solid. In this chapter, we introduce pH 2 …