Hydrogen‐atom tunneling reactions in solid para‐hydrogen and their applications to astrochemistry

KA Haupa, PR Joshi, YP Lee - Journal of the Chinese …, 2022 - Wiley Online Library
H‐atom tunneling reactions play important roles in astrochemistry, but an understanding of
these reactions is still in its infancy. The unique properties associated with quantum solid …

Unique Applications of para-Hydrogen Matrix Isolation to Spectroscopy and Astrochemistry

I Weber, PR Joshi, DT Anderson… - The Journal of Physical …, 2024 - ACS Publications
Cryogenic solid para-hydrogen (p-H2) exhibits pronounced quantum effects, enabling
unique experiments that are typically not possible in noble-gas matrices. The diminished …

Non-energetic, Low-Temperature Formation of Cα-Glycyl Radical, a Potential Interstellar Precursor of Natural Amino Acids

A Schneiker, S Góbi, PR Joshi, G Bazsó… - The Journal of …, 2021 - ACS Publications
The reaction of H atoms with glycine was investigated at 3.1 K in para-H2, a quantum-solid
host. The reaction was followed by IR spectroscopy, with the spectral analysis aided by …

A chemical link between methylamine and methylene imine and implications for interstellar glycine formation

PR Joshi, YP Lee - Communications chemistry, 2022 - nature.com
Methylamine CH3NH2 is considered to be an important precursor of interstellar amino acid
because hydrogen abstraction might lead to the aminomethyl radical• CH2NH2 that can …

Identification of HOCHC(O)H, HOCH2CO, and HOCH2CH2O Intermediates in the Reaction of H + Glycolaldehyde in Solid Para-Hydrogen and Its Implication …

PR Joshi, YP Lee - Journal of the American Chemical Society, 2024 - ACS Publications
Glycolaldehyde [HOCH2C (O) H, GA], the primitive sugar-like molecule detected in the
interstellar medium (ISM), is a potential precursor for the synthesis of complex sugars …

Successive Hydrogenation of SO and SO2 in Solid para-H2: Formation of Elusive Small Oxoacids of Sulfur

S Gobi, IP Csonka, G Bazso… - ACS Earth and Space …, 2021 - ACS Publications
The small oxoacids of sulfur (SOS), H x SO y (x, y= 1, 2), are considered to be key reactive
intermediates in organic synthesis, biochemical processes, and atmospheric chemistry …

Potential Catalytic Role of Small Heterocycles in Interstellar H2 Formation: A Laboratory Astrochemistry Study on Furan and Its Hydrogenated Forms

A Schneiker, G Ragupathy, G Bazsó… - The Journal of Physical …, 2022 - ACS Publications
It is now well-accepted in astrochemistry that the formation of interstellar H2 is taking place
on the surface of interstellar grains. It has also been suggested a long time ago that …

Hydrogen-Atom-Assisted Uphill Isomerization of N-Methylformamide in Darkness

SY Tsai, KA Haupa, YP Lee - Journal of the American Chemical …, 2022 - ACS Publications
N-Methylformamide, HC (O) NH (CH3), is the smallest amide detected in the interstellar
medium that can exist as cis and trans isomers. We performed reactions of H atoms with …

VIZSLA—Versatile ice zigzag sublimation setup for laboratory astrochemistry

G Bazsó, IP Csonka, S Góbi, G Tarczay - Review of Scientific …, 2021 - pubs.aip.org
In this article, a new multi-functional high-vacuum astrophysical ice setup, VIZSLA (Versatile
Ice Zigzag Sublimation Setup for Laboratory Astrochemistry), is introduced. The instrument …

Spectroscopy of molecules confined in solid para-hydrogen

M Tsuge, YP Lee - Molecular and Laser Spectroscopy, 2020 - Elsevier
Solid para-hydrogen (pH 2) has emerged as a novel low-temperature matrix host with
unique characteristics associated with a quantum solid. In this chapter, we introduce pH 2 …