Hydroboration of alkynes is of special interest to researchers since it is the most
straightforward process for the synthesis of highly important vinylborane synthetic …

Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

cis-Delivery of H2 to the π-system of an unsaturated substrate is the canonical course of
metal catalyzed hydrogenation reactions. The semireduction of internal alkynes with the aid …

A dual catalyst system based on ligand exchange of two diphosphine ligands possessing
different properties in a copper complex has been devised to merge metal-and …

The metal-catalyzed (Z)-selective hydroboration of terminal alkynes is synthetically
challenging due to the usually (E)-selective nature of the hydroboration and the formation of …

This review discusses the immense progress made over recent years in metal‐free catalytic
hydroboration. Reactions with several unsaturated functional groups, such as alkynes …

Although hydroboration of simple ketones and alkynes have been well-established, little is
known about the unique hydroboration reactivity for ynones, a family of important building …

Catalytic hydroelementation of alkynes mainly with hydroboranes and hydrosilanes gives a
straightforward and atom-economical access to a wide range of vinylmetalloids, which are …

We report herein the catalytic triboration of terminal alkynes with B2pin2 (bis (pinacolato)
diboron) using readily available Cu (OAc) 2 and PnBu3. Various 1, 1, 2‐triborylalkenes, a …

Olefin hydroboration reactions provide efficient access to synthetically versatile and easily
handled organoboronic esters. In this study, we demonstrate that the commercially available …