Conspectus Catalytic atroposelective syntheses of axially chiral compounds have stimulated
extensive interest in multiple communities, such as synthetic chemistry, biochemistry, and …

Silicon-stereogenic chiral organosilanes have found increasing applications in synthetic
chemistry, medicinal chemistry, and materials science. In this context, various asymmetric …

The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …

A robust and reproducible methodology to prepare stable inorganic nanoparticles with chiral
morphology may hold the key to the practical utilization of these materials. An optimized …

Beyond esoteric interest, organocatalysis has now become one major pillar of asymmetric
catalysis. Here, we discuss how new activation modes are conquering challenging …

The proportion of approved chiral drugs and drug candidates under medical studies has
surged dramatically over the past two decades. As a consequence, the efficient synthesis of …

Chiral cyclobutene units are commonly found in natural products and biologically active
molecules. Transition-metal-catalysis has been extensively used in asymmetric synthesis of …

Organocatalysis—catalysis mediated by small chiral organic molecules—is a powerful
technology for enantioselective synthesis, and has extensive applications in traditional ionic …

The enantioselective synthesis of spirocycles has long been pursued by organic chemists.
Despite their unique 3D properties and presence in several natural products, the difficulty in …

London dispersion, which constitutes the attractive part of the famous van der Waals
potential, has long been underappreciated in molecular chemistry as an important element …