Direct (hetero) arylation polymerization: simplicity for conjugated polymer synthesis

JR Pouliot, F Grenier, JT Blaskovits, S Beaupré… - Chemical …, 2016 - ACS Publications
Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

Sustainable protocols for direct C–H bond arylation of (hetero) arenes

G Albano, A Punzi, MAM Capozzi, GM Farinola - Green Chemistry, 2022 - pubs.rsc.org
Direct C–H bond arylation of (hetero) arenes is a very convenient approach for the synthesis
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …

Tin-free direct C–H arylation polymerization for high photovoltaic efficiency conjugated copolymers

AS Dudnik, TJ Aldrich, ND Eastham… - Journal of the …, 2016 - ACS Publications
A new and highly regioselective direct C–H arylation polymerization (DARP) methodology
enables the reproducible and sustainable synthesis of high-performance π-conjugated …

Direct arylation polymerization: A guide to optimal conditions for effective conjugated polymers

NS Gobalasingham, BC Thompson - Progress in Polymer Science, 2018 - Elsevier
The rapid increase in the breadth and scope of transformations that involve metal-promoted
activation of Csingle bondH bonds is fundamentally changing the field of synthetic …

Recent development of quinoxaline based polymers/small molecules for organic photovoltaics

D Gedefaw, M Prosa, M Bolognesi… - Advanced Energy …, 2017 - Wiley Online Library
Among the various molecular designs developed for the synthesis of conjugated polymers
and small molecules for optoelectronic applications, the donor: acceptor (D–A) approach is …

Development of quinoxaline based polymers for photovoltaic applications

J Yuan, J Ouyang, V Cimrová, M Leclerc… - Journal of Materials …, 2017 - pubs.rsc.org
Polymer solar cells (PSCs) with a bulk heterojunction (BHJ) structure, ie a blend of a p-type
conjugated polymer with an n-type semiconductor acceptor, have made rapid progress over …

Eco‐friendly solvent‐processed fullerene‐free polymer solar cells with over 9.7% efficiency and long‐term performance stability

GE Park, S Choi, SY Park, DH Lee… - Advanced Energy …, 2017 - Wiley Online Library
A wide‐bandgap polymer,(poly [(2, 6‐(4, 8‐bis (5‐(2‐ethylhexyl) thiophen‐2‐yl)‐benzo [1, 2‐
b: 4, 5‐b′] dithiophene))‐alt‐(2, 5‐(methyl thiophene carboxylate))])(3MT‐Th), is …

Quinoxaline-based conjugated polymers for polymer solar cells

M Liu, Y Gao, Y Zhang, Z Liu, L Zhao - Polymer Chemistry, 2017 - pubs.rsc.org
Bulk heterojunction (BHJ) polymer solar cells (PSCs), as a promising alternative to
conventional silicon-based solar cells, have achieved rapid development in recent years. In …

Near-infrared absorbing non-fullerene acceptors with selenophene as π bridges for efficient organic solar cells

Z Liang, M Li, X Zhang, Q Wang, Y Jiang… - Journal of Materials …, 2018 - pubs.rsc.org
Two non-fullerene acceptors with selenophene π bridges to link the indacenodithiophene
(IDT) core and 3-(dicyanomethylidene) indan-1-one (IC) or difluorinated IC (2F-IC) terminals …

Significantly improved morphology and efficiency of nonhalogenated solvent‐processed solar cells derived from a conjugated donor–acceptor block copolymer

SH Park, Y Kim, NY Kwon, YW Lee, HY Woo… - Advanced …, 2020 - Wiley Online Library
A highly crystalline conjugated donor (D)–acceptor (A) block copolymer (PBDT2T‐b‐N2200)
that has good solubility in nonhalogenated solvents is successfully synthesized. PBDT2T‐b …