Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …

Metallaaromatics can be broadly defined as aromatic compounds in which one of the ring
atoms is a transition metal. The metallabenzenes are one important class of these …

Chemical transformations that result in either the formation or cleavage of carbon–
heteroatom bonds are among the most important processes in the chemical sciences …

Nickel PCP-pincer hydride complexes catalyze chemoselective hydrosilylation of C O
bonds of aldehydes and ketones in the presence of other functional groups. The mechanism …

The chemistry of late-transition-metal complexes possessing amido (NR2-) and imido (NR2-
) ligands is much less developed than that of the early-and mid-transition elements. 1 This is …

Sulfur-based ligands are versatile donors that play important roles in a wide array of
subdisciplines of inorganic chemistry including organometallic chemistry, bioinorganic …

Mechanistic studies of the hydrogenolysis of aryl ethers by nickel were undertaken with
(diphosphine) aryl methyl ethers. A Ni (0) complex containing Ni–arene interactions …

A nickel‐catalyzed aryl thioether metathesis has been developed to access high‐value
thioethers. 1, 2‐Bis (dicyclohexylphosphino) ethane (dcype) is essential to promote this …

A Rh (I)-catalyzed method for the efficient functionalization of arenes is reported. Aryl methyl
sulfides are combined with terminal alkynes to deliver products of carbothiolation. The …

The development of metalated covalent organic frameworks (COFs) is useful for generating
recyclable catalytic systems for practical applications. Herein, we report the synthesis …