Metal-Free Catalysis: A Redox-Active Donor–Acceptor Conjugated Microporous Polymer for Selective Visible-Light-Driven CO2 Reduction to CH4

S Barman, A Singh, FA Rahimi… - Journal of the American …, 2021 - ACS Publications
Achieving more than a two-electron photochemical CO2 reduction process using a metal-
free system is quite exciting and challenging, as it needs proper channeling of electrons. In …

Covalent grafting of molecular photosensitizer and catalyst on MOF-808: effect of pore confinement toward visible light-driven CO 2 reduction in water

S Karmakar, S Barman, FA Rahimi… - Energy & Environmental …, 2021 - pubs.rsc.org
The photocatalytic reduction of CO2 in water using a single integrated system utilizing
sunlight is the ultimate goal for artificial photosynthesis. Here, we report the design and …

Advance and prospective on CO2 activation and transformation strategy

K Chen, H Li, L He - Chinese Journal of Organic Chemistry, 2020 - sioc-journal.cn
Climate change and depletion of fossil fuels have drawn considerable attention.
Considering carbon dioxide is both the dominant greenhouse gas and renewable C 1 …

GFP Chromophore Integrated Conjugated Microporous Polymers toward Bioinspired Photocatalytic CO2 Reduction to CO

FA Rahimi, A Singh, R Jena, A Dey… - ACS Applied Materials & …, 2024 - ACS Publications
The development of highly active, durable, and low-cost metal-free catalysts for the
photocatalytic CO2 reduction reaction (CO2RR) is an efficient and environmentally friendly …

Soft-oxometalates (SOMs): crafting the pillars of a sustainable future

N Kumari, S Roy - Journal of Materials Chemistry A, 2024 - pubs.rsc.org
Sustainability stands as a pivotal challenge in advancing new technologies and fostering
innovation. The unique attributes of soft-oxometalate pave the way for constructing a …

Coassembly of short peptide and polyoxometalate into complex coacervate adapted for pH and metal ion-triggered underwater adhesion

X Li, T Zheng, X Liu, Z Du, X Xie, B Li, L Wu, W Li - Langmuir, 2019 - ACS Publications
The fabrication of peptide assemblies to mimic the functions of natural proteins represents
an intriguing aim in the fields of soft materials. Herein, we present a kind of novel peptide …

En route to artificial photosynthesis: the role of polyoxometalate based photocatalysts

A Paul, SD Adhikary, S Kapurwan… - Journal of Materials …, 2022 - pubs.rsc.org
As a consequence of increasing global energy demand and depleting fossil fuels, artificial
photosynthesis, ie, subsequent photocatalytic water oxidation and CO2 reduction, has …

[HTML][HTML] Coordinatively fluxional diazo-based organo-electrocatalyst for conversion of CO2 to C2 and C3 products

N Kumari, S Halder, S Naskar, S Ganguly… - Materials Today …, 2024 - Elsevier
The conversion of carbon dioxide (CO 2) into valuable chemicals, specifically C 2 and C 3,
through metal-free electrocatalysis remains a formidable challenge. Breaking away from …

Visible light driven catalytic gold decorated soft-oxometalate (SOM) based nanomotors for organic pollutant remediation

A Mallick, S Roy - Nanoscale, 2018 - pubs.rsc.org
Visible light propelled nanomotors are a class of highly sought after active matter. Here we
report a gold decorated semiconductor and a soft-oxometalate based TiO2-{Mo7}-Au …

Light-driven carbon dioxide reduction coupled with conversion of acetylenic group to ketone by a functional Janus catalyst based on keplerate {Mo 132}

J Lodh, A Mallick, S Roy - Journal of Materials Chemistry A, 2018 - pubs.rsc.org
Catalysts enabling CO2 reduction coupled with another organic reaction are rare. In this
study, we report such a catalyst keplerate {Mo132}, which catalyses photochemical carbon …