Recent studies unveiled two unprecedented phenomena which together may induce a
paradigm shift in understanding chemical reactivity in solutions which would no longer be …

Solvent effect is a vital subject in the domain of coordination chemistry. In this connection,
previous researches mainly focus on the role of solvents in reaction kinetics and …

Stereodivergent catalysis, the art of accessing multiple stereoisomers from the same starting
materials, has been a keystone of modern organic chemistry. Among the numerous factors …

The world is chiral. Most of the molecules in it are chiral, and asymmetric synthesis is an
important means by which enantiopure chiral molecules may be obtained for study and sale …

Here, we used an unconventional idea of cooperative vibrational strong coupling of solute
and solvent molecules to enhance the rate of an esterification reaction. Different derivatives …

In this work, we describe an efficient and modular method for enantiodivergent accessing P
(V)‐stereogenic molecules by utilizing the catalytic atroposelective Catellani‐type C− H …

A decarboxylative protocol has been developed toward a range of carbocycles. The key
success is based on the use of a batch of newly designed cyclic carbonates as substrates …

Solvents can significantly influence chemical reactions in condensed phases. Their critical
properties are increasingly recognized in various research domains such as organic …

Controlling reaction selectivity is a permanent pursuit for chemists. Regioselective catalysis,
which exploits and/or overcomes innate steric and electronic bias to deliver diverse regio …

We provide insights into the effects of stable and verifiable, low‐temperature conditions on
mechanochemical reactions. These are made possible by modifications made to a SPEX …