Non-universal features in uniaxially extensional rheology of linear polymer melts and concentrated solutions: A review
Y Matsumiya, H Watanabe - Progress in Polymer Science, 2021 - Elsevier
Rheological behavior of polymeric liquids has been considered to be universally determined
by a few time-independent molecular parameters (such as the Rouse relaxation time and …
by a few time-independent molecular parameters (such as the Rouse relaxation time and …
Modeling the rheology of polymer melts and solutions
We review constitutive modeling of solutions and melts of linear polymers, focusing on
changes in rheological behavior in shear and extensional flow as the concentration …
changes in rheological behavior in shear and extensional flow as the concentration …
Advances and new opportunities in the rheology of physically and chemically reversible polymers
S Wu, Q Chen - Macromolecules, 2021 - ACS Publications
The advances in understanding the dynamics of both the physically and chemically
reversible networks are summarized from a rheological perspective. The focus is placed on …
reversible networks are summarized from a rheological perspective. The focus is placed on …
Physics of liquid jets
J Eggers, E Villermaux - Reports on progress in physics, 2008 - iopscience.iop.org
Jets, ie collimated streams of matter, occur from the microscale up to the large-scale
structure of the universe. Our focus will be mostly on surface tension effects, which result …
structure of the universe. Our focus will be mostly on surface tension effects, which result …
When polymer chains are highly aligned: a perspective on extensional rheology
Q Huang - Macromolecules, 2022 - ACS Publications
We provide a Perspective on recent findings in extensional rheology for polymer melts and
solutions with different macromolecular architectures. For linear polymer systems, we focus …
solutions with different macromolecular architectures. For linear polymer systems, we focus …
Concentrated polymer solutions are different from melts: Role of entanglement molecular weight
Q Huang, O Mednova, HK Rasmussen… - …, 2013 - ACS Publications
We compare viscoelastic properties of several polystyrene solutions and melts with the
same number of entanglements. It is demonstrated that the modulus and time can be shifted …
same number of entanglements. It is demonstrated that the modulus and time can be shifted …
Measuring the transient extensional rheology of polyethylene melts using the SER universal testing platform
M Sentmanat, BN Wang, GH McKinley - Journal of rheology, 2005 - pubs.aip.org
We use a new extensional rheology test fixture that has been developed for conventional
torsional rheometers to measure the transient extensional stress growth in a number of …
torsional rheometers to measure the transient extensional stress growth in a number of …
Unexpected stretching of entangled ring macromolecules
In the melt state at equilibrium, entangled nonconcatenated ring macromolecules adapt
more compact conformations compared to their linear analogs and do not form an …
more compact conformations compared to their linear analogs and do not form an …
Extensional rheology of a shear-thickening cornstarch and water suspension
EE Bischoff White, M Chellamuthu, JP Rothstein - Rheologica acta, 2010 - Springer
A filament-stretching rheometer is used to measure the extensional viscosity of a shear-
thickening suspension of cornstarch in water. The experiments are performed at a …
thickening suspension of cornstarch in water. The experiments are performed at a …
Primitive chain network simulation of elongational flows of entangled linear chains: Stretch/orientation-induced reduction of monomeric friction
T Yaoita, T Isaki, Y Masubuchi, H Watanabe… - …, 2012 - ACS Publications
Well-entangled monodisperse linear polystyrene melts exhibit monotonic thinning of the
steady state elongational viscosity with increasing the strain rate ε̇ even beyond the Rouse …
steady state elongational viscosity with increasing the strain rate ε̇ even beyond the Rouse …