Hydrovinylation Reactions–Atom‐Economic Transformations with Steadily Increasing Synthetic Potential

G Hilt - European Journal of Organic Chemistry, 2012 - Wiley Online Library
The intermolecular carbon–carbon bond formation between two alkenes also known as 1, 2‐
hydrovinylation reaction can be realised with different transition metal catalysts. The …

In pursuit of an ideal carbon-carbon bond-forming reaction: development and applications of the hydrovinylation of olefins

TV RajanBabu - Synlett, 2009 - thieme-connect.com
Attempts to introduce the highly versatile vinyl group into other organic molecules in a
chemo-, regio-, and stereoselective fashion via catalytic activation of ethylene provided …

Selective [1, 4]-hydrovinylation of 1, 3-dienes with unactivated olefins enabled by iron diimine catalysts

VA Schmidt, CR Kennedy, MJ Bezdek… - Journal of the American …, 2018 - ACS Publications
The selective, intermolecular [1, 4]-hydrovinylation of conjugated dienes with unactivated α-
olefins catalyzed by α-diimine iron complexes is described. Value-added “skipped” diene …

Asymmetric hydrovinylation of unactivated linear 1, 3-dienes

RK Sharma, TV RajanBabu - Journal of the American Chemical …, 2010 - ACS Publications
Monosubstituted acyclic (E)-1, 3-dienes undergo efficient hydrovinylation giving (Z)-3-
alkylhexa-1, 4-dienes upon treatment with catalytic amounts of bidentate phosphine-CoCl2 …

Recent advances in the catalytic linear cross-dimerizations

M Hirano - ACS Catalysis, 2019 - ACS Publications
Catalytic cross-dimerization is one of the powerful synthetic methods to produce linear
molecules with high atom and step economy. Because this process involves a carbon …

Highly selective cobalt-catalyzed hydrovinylation of styrene

MMP Grutters, C Müller, D Vogt - Journal of the American …, 2006 - ACS Publications
The hydrovinylation reaction is a codimerization of a 1, 3-diene or vinyl arene and ethene
with great potential for fine chemicals and pharmaceuticals. For the first time …

Asymmetric hydrovinylation of 1-vinylcycloalkenes. Reagent control of regio-and stereoselectivity

JP Page, TV RajanBabu - Journal of the American Chemical …, 2012 - ACS Publications
1-Vinylcycloalkenes undergo highly regio-and enantioselective (> 98% ee) 1, 4-
hydrovinylation (HV) when treated with ethylene (1 atm) at room temperature in the …

Hydrovinylation of 1, 3-dienes: a new protocol, an asymmetric variation, and a potential solution to the exocyclic side chain stereochemistry problem

A Zhang, TV RajanBabu - Journal of the American Chemical …, 2006 - ACS Publications
Cyclic and acyclic 1, 3-dienes undergo efficient (substrate/catalyst= 72) heterodimerization
with ethylene in the presence of a Ni catalyst prepared from [o-(PhCH2O)] C6H4PPh2,[(allyl) …

Cobalt-catalysed asymmetric hydrovinylation of 1, 3-dienes

YN Timsina, RK Sharma, TV RajanBabu - Chemical science, 2015 - pubs.rsc.org
In the presence of bidentate 1, n-bis-diphenylphosphinoalkane-CoCl2 complexes {Cl2Co
[P∼ P]} and Me3Al or methylaluminoxane, acyclic (E)-1, 3-dienes react with ethylene (1 …

Heterodimerization of olefins. 1. Hydrovinylation reactions of olefins that are amenable to asymmetric catalysis

TV RajanBabu, N Nomura, J Jin, M Nandi… - The Journal of …, 2003 - ACS Publications
Through a systematic examination of ligand and counterion effects, new protocols for a
nearly quantitative and highly selective codimerization of ethylene and various …