Sulfonyl fluorides as targets and substrates in the development of new synthetic methods
The advent of sulfur (vi)-fluoride exchange (SuFEx) processes as transformations with click-
like reactivity has invigorated research into electrophilic species featuring a sulfur–fluorine …
like reactivity has invigorated research into electrophilic species featuring a sulfur–fluorine …
Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds
F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …
The growing applications of SuFEx click chemistry
SuFEx (Sulfur Fluoride Exchange) is a modular, next generation family of click reactions,
geared towards the rapid and reliable assembly of functional molecules. This review …
geared towards the rapid and reliable assembly of functional molecules. This review …
Radical Hydro‐Fluorosulfonylation of Unactivated Alkenes and Alkynes
P Wang, H Zhang, M Zhao, S Ji, L Lin… - Angewandte Chemie …, 2022 - Wiley Online Library
Recently, radical fluorosulfonylation is emerging as an appealing approach for the synthesis
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …
The emerging applications of sulfur (VI) fluorides in catalysis
C Lee, AJ Cook, JE Elisabeth, NC Friede… - ACS …, 2021 - ACS Publications
The past decade has witnessed remarkable growth of catalytic transformations in organic
sulfur (VI) fluoride chemistry. This Perspective concentrates exclusively on foundational …
sulfur (VI) fluoride chemistry. This Perspective concentrates exclusively on foundational …
A practical fluorosulfonylating platform via photocatalytic imidazolium-based SO2F radical reagent
W Zhang, H Li, X Li, Z Zou, M Huang, J Liu… - Nature …, 2022 - nature.com
Sulfonyl fluorides are key components in the fields of chemical biology, materials science
and drug discovery. In this line, the highly active SO2F radical has been employed for the …
and drug discovery. In this line, the highly active SO2F radical has been employed for the …
Chemical and biology of sulfur fluoride exchange (SuFEx) click chemistry for drug discovery
Compounds containing an Ssingle bondF bond have garnered intense interest in the
chemical and biological literature. In particular, sulfonyl fluorides (RSO 2 F) are commonly …
chemical and biological literature. In particular, sulfonyl fluorides (RSO 2 F) are commonly …
Photoredox catalytic radical fluorosulfonylation of olefins enabled by a bench-stable redox-active fluorosulfonyl radical precursor
P Wang, H Zhang, X Nie, T Xu, S Liao - Nature Communications, 2022 - nature.com
Sulfonyl fluorides have attracted considerable and growing research interests from various
disciplines, which raises a high demand for novel and effective methods to access this class …
disciplines, which raises a high demand for novel and effective methods to access this class …
Electrochemical Oxo‐Fluorosulfonylation of Alkynes under Air: Facile Access to β‐Keto Sulfonyl Fluorides
D Chen, X Nie, Q Feng, Y Zhang… - Angewandte Chemie …, 2021 - Wiley Online Library
Radical fluorosulfonylation is emerging as an appealing approach for the synthesis of
sulfonyl fluorides, which have widespread applications in many fields, in particular in the …
sulfonyl fluorides, which have widespread applications in many fields, in particular in the …
SuFEx-enabled, agnostic discovery of covalent inhibitors of human neutrophil elastase
Sulfur fluoride exchange (SuFEx) has emerged as the new generation of click chemistry. We
report here a SuFEx-enabled, agnostic approach for the discovery and optimization of …
report here a SuFEx-enabled, agnostic approach for the discovery and optimization of …