Single-atom alloy catalysis

RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …

Low-temperature liquid platinum catalyst

MA Rahim, J Tang, AJ Christofferson, PV Kumar… - Nature Chemistry, 2022 - nature.com
Insights into metal–matrix interactions in atomically dispersed catalytic systems are
necessary to exploit the true catalytic activity of isolated metal atoms. Distinct from catalytic …

Propylene synthesis: Recent advances in the use of Pt-based catalysts for propane dehydrogenation reaction

M Martino, E Meloni, G Festa, V Palma - Catalysts, 2021 - mdpi.com
Propylene is one of the most important feedstocks in the chemical industry, as it is used in
the production of widely diffused materials such as polypropylene. Conventionally …

GaPt supported catalytically active liquid metal solution catalysis for propane dehydrogenation–support influence and coking studies

N Raman, M Wolf, M Heller, N Heene-Würl… - ACS …, 2021 - ACS Publications
Supported catalytically active liquid metal solutions (SCALMS) of Pt in Ga (2 at.-% Pt) were
studied in the temperature range of 500 to 600° C for propane dehydrogenation. A facile …

Ga–Pt supported catalytically active liquid metal solutions (SCALMS) prepared by ultrasonication–influence of synthesis conditions on n-heptane dehydrogenation …

O Sebastian, A Al-Shaibani, N Taccardi… - Catalysis Science & …, 2023 - pubs.rsc.org
Supported catalytically active liquid metal solution (SCALMS) materials represent a recently
developed class of heterogeneous catalysts, where the catalytic reaction takes place at the …

Dry reforming of methane over gallium-based supported catalytically active liquid metal solutions

M Wolf, AL de Oliveira, N Taccardi, S Maisel… - Communications …, 2023 - nature.com
Gallium-rich supported catalytically active liquid metal solutions (SCALMS) were recently
introduced as a new way towards heterogeneous single atom catalysis. SCALMS were …

Supraparticles on beads for supported catalytically active liquid metal solutions–the SCALMS suprabead concept

T Zimmermann, N Madubuko, P Groppe, T Raczka… - Materials …, 2023 - pubs.rsc.org
A novel GaPt-based supported catalytically active liquid metal solution (SCALMS) material is
developed by exploiting the suprabead concept: Supraparticles, ie micrometer-sized …

Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization

A Søgaard, AL de Oliveira, N Taccardi… - Catalysis science & …, 2021 - pubs.rsc.org
Non-precious metal supported catalytically active liquid metal solutions exhibit attractive
performance in ethylene oligomerization. It is found for the Ga–Ni system on silica that the …

Production of low carbon number olefins from natural gas: Methane-involved catalytic non-oxidative propane dehydrogenation

H Xu, M Cao, Z Li, W Li, S Meng, H Song - Chemical Engineering Journal, 2023 - Elsevier
Low carbon number olefins such as ethylene and propylene are important chemical
products with large production and extensive usage. Natural gas is a clean and abundant …

Unraveling the Effect of Rh Isolation on Shallow d States of Gallium–Rhodium Alloys

TE Hsieh, S Maisel, H Wittkämper… - The Journal of …, 2023 - ACS Publications
In this study, we report the electronic and chemical structure of supported GaRh alloys as
model systems for the active phase in supported catalytically active liquid metal solutions …