Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

The functionalization of C–H bonds in organic molecules containing functional groups has
been one of the holy grails of catalysis. One synthetically important approach to the diverse …

Iridium-catalyzed C–H activation and borylation has become as a powerful synthetic tool in
the past few decades because of the widespread applicability and versatility of organoboron …

Rendering a common ligand scaffold anionic and then pairing it with a chiral cation
represents an alternative strategy for developing enantioselective versions of challenging …

Anilines are important moieties in organic chemistry, pharmaceuticals, and materials
science. Although para-selective functionalization of anilides and tertiary anilines is well …

C–H borylation is one of the powerful C–H bond functionalization reactions. In this context, a
metal-free C–H borylation of benzophenones using hydrazone as the traceless directing …

Aryl sulfones and aryl sulfonamides are of great importance in organic synthesis and
medicinal chemistry. Although ortho‐C− H functionalization of aryl sulfonyl compounds has …

A new catalytic method for para borylation of unprotected anilines is described. The catalytic
method is developed by designing a new type of ligand framework that enables para …

Herein, we disclose a mild and versatile nickel-catalyzed method for exclusive C3-selective
thioetherification, alkylation, arylation, acylation, and phosphorylation of quinolines with a …

Exploitation of noncovalent interactions for recognition of an organic substrate has received
much attention for the design of metal catalysts in organic synthesis. The CH–π interaction is …