Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration

L Capaldo, D Ravelli, M Fagnoni - Chemical Reviews, 2021 - ACS Publications
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Aryl transfer strategies mediated by photoinduced electron transfer

AR Allen, EA Noten, CRJ Stephenson - Chemical reviews, 2021 - ACS Publications
Radical aryl migrations are powerful techniques to forge new bonds in aromatic compounds.
The growing popularity of photoredox catalysis has led to an influx of novel strategies to …

Carbon–carbon bond forming reactions via photogenerated intermediates

D Ravelli, S Protti, M Fagnoni - Chemical reviews, 2016 - ACS Publications
The present review offers an overview of the current approaches for the photochemical and
photocatalytic generation of reactive intermediates and their application in the formation of …

Site-selective C–H functionalization by decatungstate anion photocatalysis: synergistic control by polar and steric effects expands the reaction scope

D Ravelli, M Fagnoni, T Fukuyama, T Nishikawa… - ACS …, 2018 - ACS Publications
The synergistic control of the SH2 transition states of hydrogen abstraction by polar and
steric effects provides a promising strategy in achieving site-selective C (sp3)–H …

Catalytic alkylation of unactivated C (sp 3)–H bonds for C (sp 3)–C (sp 3) bond formation

Z Chen, MY Rong, J Nie, XF Zhu, BF Shi… - Chemical Society …, 2019 - pubs.rsc.org
The construction of carbon–carbon bonds is a central tenet of modern synthetic chemistry.
Metal-catalyzed C–H functionalization can serve as a particularly powerful tool for achieving …

Polyoxometalate photocatalysis for liquid-phase selective organic functional group transformations

K Suzuki, N Mizuno, K Yamaguchi - ACS Catalysis, 2018 - ACS Publications
Polyoxometalates (POMs), which are anionic metal oxide clusters, have recently attracted
considerable attention as photocatalysts because of their unique photoinduced charge …

Photochemical reactions as key steps in organic synthesis

N Hoffmann - Chemical Reviews, 2008 - ACS Publications
Since the beginning of scientific chemistry, chemists have been interested in light as an
energy source to induce chemical reactions. 1 Absorbing light, molecules reach an …

Photocatalysis for the Formation of the C− C Bond

M Fagnoni, D Dondi, D Ravelli, A Albini - Chemical Reviews, 2007 - ACS Publications
Carbon-carbon bond formation is the core of organic synthesis and has been greatly
changed in the last decades by the development of transition metal-catalyzed processes. 1 …

Photocatalysis: a promising route for 21st century organic chemistry

G Palmisano, V Augugliaro, M Pagliaro… - Chemical …, 2007 - pubs.rsc.org
One of the main goals of 21st century chemistry is to replace environmentally hazardous
processes with energy efficient routes allowing to totally avoid the use and production of …

Decatungstate as an efficient photocatalyst in organic chemistry

MD Tzirakis, IN Lykakis, M Orfanopoulos - Chemical Society Reviews, 2009 - pubs.rsc.org
In view of its unique photocatalytic properties, decatungstate (W10O324−) is rapidly
emerging as a promising tool in organic chemistry. This tutorial review surveys recent …