Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
Aryl transfer strategies mediated by photoinduced electron transfer
Radical aryl migrations are powerful techniques to forge new bonds in aromatic compounds.
The growing popularity of photoredox catalysis has led to an influx of novel strategies to …
The growing popularity of photoredox catalysis has led to an influx of novel strategies to …
Carbon–carbon bond forming reactions via photogenerated intermediates
The present review offers an overview of the current approaches for the photochemical and
photocatalytic generation of reactive intermediates and their application in the formation of …
photocatalytic generation of reactive intermediates and their application in the formation of …
Site-selective C–H functionalization by decatungstate anion photocatalysis: synergistic control by polar and steric effects expands the reaction scope
The synergistic control of the SH2 transition states of hydrogen abstraction by polar and
steric effects provides a promising strategy in achieving site-selective C (sp3)–H …
steric effects provides a promising strategy in achieving site-selective C (sp3)–H …
Catalytic alkylation of unactivated C (sp 3)–H bonds for C (sp 3)–C (sp 3) bond formation
The construction of carbon–carbon bonds is a central tenet of modern synthetic chemistry.
Metal-catalyzed C–H functionalization can serve as a particularly powerful tool for achieving …
Metal-catalyzed C–H functionalization can serve as a particularly powerful tool for achieving …
Polyoxometalate photocatalysis for liquid-phase selective organic functional group transformations
K Suzuki, N Mizuno, K Yamaguchi - ACS Catalysis, 2018 - ACS Publications
Polyoxometalates (POMs), which are anionic metal oxide clusters, have recently attracted
considerable attention as photocatalysts because of their unique photoinduced charge …
considerable attention as photocatalysts because of their unique photoinduced charge …
Photochemical reactions as key steps in organic synthesis
N Hoffmann - Chemical Reviews, 2008 - ACS Publications
Since the beginning of scientific chemistry, chemists have been interested in light as an
energy source to induce chemical reactions. 1 Absorbing light, molecules reach an …
energy source to induce chemical reactions. 1 Absorbing light, molecules reach an …
Photocatalysis for the Formation of the C− C Bond
Carbon-carbon bond formation is the core of organic synthesis and has been greatly
changed in the last decades by the development of transition metal-catalyzed processes. 1 …
changed in the last decades by the development of transition metal-catalyzed processes. 1 …
Photocatalysis: a promising route for 21st century organic chemistry
One of the main goals of 21st century chemistry is to replace environmentally hazardous
processes with energy efficient routes allowing to totally avoid the use and production of …
processes with energy efficient routes allowing to totally avoid the use and production of …
Decatungstate as an efficient photocatalyst in organic chemistry
MD Tzirakis, IN Lykakis, M Orfanopoulos - Chemical Society Reviews, 2009 - pubs.rsc.org
In view of its unique photocatalytic properties, decatungstate (W10O324−) is rapidly
emerging as a promising tool in organic chemistry. This tutorial review surveys recent …
emerging as a promising tool in organic chemistry. This tutorial review surveys recent …