Axially chiral compounds are a result of the nonplanar arrangement of four groups in pairs
about a chirality axis. Axially chiral molecules not only exist in a range of bioactive …

The C− N axially chiral N-arylpyrrole motifs are privileged scaffolds in numerous biologically
active molecules and natural products, as well as in chiral ligands/catalysts. Asymmetric …

An unprecedented decomposition of unprotected alkynyl hydrazones is attempted that has
provided allenoates, tetrasubstituted α, γ-dihaloallenoates, and functionalized tricyclic …

Abstract Herein, copper-catalyzed 1, 4-protosilylation and 1, 4-protoborylation of enynic
orthoesters have been developed. The enynic orthoesters as precursors of unstable enynic …

An asymmetric Michael addition/hydroarylation reaction sequence, catalyzed by a
sequential catalytic system consisting of a squaramide and a combination of silver and gold …

Enantioselective synthesis of eight-membered N-heterocycles represents a long-standing
challenge in organic synthesis. Here, by combining the squaramide and DBU catalysis, a …

A systematized survey of reviews and monographs published in 2021 on all aspects of
heterocyclic chemistry is given. Methods for the synthesis, reactivity, and practically useful …

The asymmetric hydrogenation of β-alkynyl α, β-unsaturated ketones has been achieved by
using Ir/f-phamidol as a catalyst under mild conditions, providing the corresponding chiral …

An effective organocatalytic protocol toward the assembly of symmetrical and unsymmetrical
2, 6‐diarylpyridines is demonstrated. The reaction proceeds through organocatalytic …

A palladium-promoted cascade cyclization of 5-(2-bromophenyl) pent-3-en-1-ynes is
developed for the synthesis of benzo [a] fluorene derivatives. The reaction proceeds with …