Alkane oxidation: methane monooxygenases, related enzymes, and their biomimetics
VCC Wang, S Maji, PPY Chen, HK Lee, SSF Yu… - Chemical …, 2017 - ACS Publications
Methane monooxygenases (MMOs) mediate the facile conversion of methane into methanol
in methanotrophic bacteria with high efficiency under ambient conditions. Because the …
in methanotrophic bacteria with high efficiency under ambient conditions. Because the …
Copper active sites in biology
EI Solomon, DE Heppner, EM Johnston… - Chemical …, 2014 - ACS Publications
On the basis of its generally accessible I/II redox couple and bioavailability, copper plays a
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …
Iron and copper active sites in zeolites and their correlation to metalloenzymes
BER Snyder, ML Bols, RA Schoonheydt… - Chemical …, 2017 - ACS Publications
Metal-exchanged zeolites are a class of heterogeneous catalysts that perform important
functions ranging from selective hydrocarbon oxidation to remediation of NO x pollutants …
functions ranging from selective hydrocarbon oxidation to remediation of NO x pollutants …
Recovery of particulate methane monooxygenase structure and activity in a lipid bilayer
Bacterial methane oxidation using the enzyme particulate methane monooxygenase
(pMMO) contributes to the removal of environmental methane, a potent greenhouse gas …
(pMMO) contributes to the removal of environmental methane, a potent greenhouse gas …
Biochemistry of aerobic biological methane oxidation
CW Koo, AC Rosenzweig - Chemical Society Reviews, 2021 - pubs.rsc.org
Methanotrophic bacteria represent a potential route to methane utilization and mitigation of
methane emissions. In the first step of their metabolic pathway, aerobic methanotrophs use …
methane emissions. In the first step of their metabolic pathway, aerobic methanotrophs use …
A tale of two methane monooxygenases
MO Ross, AC Rosenzweig - JBIC Journal of Biological Inorganic …, 2017 - Springer
Methane monooxygenase (MMO) enzymes activate O 2 for oxidation of methane. Two
distinct MMOs exist in nature, a soluble form that uses a diiron active site (sMMO) and a …
distinct MMOs exist in nature, a soluble form that uses a diiron active site (sMMO) and a …
Enzymatic oxidation of methane
S Sirajuddin, AC Rosenzweig - Biochemistry, 2015 - ACS Publications
Methane monooxygenases (MMOs) are enzymes that catalyze the oxidation of methane to
methanol in methanotrophic bacteria. As potential targets for new gas-to-liquid methane …
methanol in methanotrophic bacteria. As potential targets for new gas-to-liquid methane …
Direct Methane Oxidation by Copper-and Iron-Dependent Methane Monooxygenases
FJ Tucci, AC Rosenzweig - Chemical reviews, 2024 - ACS Publications
Methane is a potent greenhouse gas that contributes significantly to climate change and is
primarily regulated in Nature by methanotrophic bacteria, which consume methane gas as …
primarily regulated in Nature by methanotrophic bacteria, which consume methane gas as …
Formation of [Cu2O2]2+ and [Cu2O]2+ toward C–H Bond Activation in Cu-SSZ-13 and Cu-SSZ-39
Cu-exchanged small-pore zeolites (CHA and AEI) form methanol from methane (> 95%
selectivity) using a 3-step cyclic procedure (Wulfers et al. Chem. Commun. 2015, 51, 4447 …
selectivity) using a 3-step cyclic procedure (Wulfers et al. Chem. Commun. 2015, 51, 4447 …
Oxidation of methane by a biological dicopper centre
R Balasubramanian, SM Smith, S Rawat, LA Yatsunyk… - Nature, 2010 - nature.com
Vast world reserves of methane gas are underutilized as a feedstock for the production of
liquid fuels and chemicals owing to the lack of economical and sustainable strategies for the …
liquid fuels and chemicals owing to the lack of economical and sustainable strategies for the …