Metallacarborane cluster anions of the cobalt bisdicarbollide-type as chaotropic carriers for transmembrane and intracellular delivery of cationic peptides

Y Chen, A Barba-Bon, B Grüner… - Journal of the …, 2023 - ACS Publications
Cobalt bisdicarbollides (COSANs) are inorganic boron-based anions that have been
previously reported to permeate by themselves through lipid bilayer membranes, a …

Metallacarboranes in Medicinal Chemistry: Current Advances and Future Perspectives

M Gos, J Cebula, TM Goszczyński - Journal of Medicinal …, 2024 - ACS Publications
Metallacarboranes, exemplified by cobalt bis (dicarbollide)([COSAN]−), have excelled their
historical metallocene analogue label to become promising in drug design, medical studies …

[HTML][HTML] Bis (Dicarbollide) Complexes of Transition Metals: How Substituents in Dicarbollide Ligands Affect the Geometry and Properties of the Complexes

IB Sivaev - Molecules, 2024 - mdpi.com
The interaction between different types of substituents in dicarbollide ligands and their
influence on the stabilization of various rotational conformers (rotamers) of transition metal …

New Boron Containing Acridines: Synthesis and Preliminary Biological Study

AA Druzina, NV Dudarova, IV Ananyev, AA Antonets… - Molecules, 2023 - mdpi.com
The synthesis of the first conjugates of acridine with cobalt bis (dicarbollide) are reported. A
novel 9-azido derivative of acridine was prepared through the reaction of 9-methoxyacridine …

Unraveling the Correlation between Biological Effects and Halogen Substituents in Cobalt bis (dicarbollide)

K Zakręt-Drozdowska, B Szermer-Olearnik… - 2024 - chemrxiv.org
Over the past decade, considerable scientific attention has been given to adapting cobalt bis
(dicarbollides) as innovative agents with various biomedical applications. Although the …