Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

The chemistry of f-block metal–carbon multiple bonds is underdeveloped compared to well-
established carbene complexes of the d-block transition metals. Herein, we report two new …

There is a growing interest in uranium coordination chemistry, particularly as it relates to
metal–ligand multiple bonding, and in the last decade significant progress has been made …

Despite decades of efforts, the actinide–carbon triple bond has remained an elusive target,
defying synthesis in any isolable compound. Herein, we report the successful synthesis of …

Bis zum Jahr 2000 umfasste die nichtwässrige Uranchemie hauptsächlich Metallocen‐und
klassische Alkyl‐, Amid‐oder Alkoxidverbindungen sowie bekannte Carben‐, Imido‐und …

Understanding the bonding, reactivity and electronic structure of actinides is lagging behind
that of the rest of the periodic table. This can be partly explained by the challenges that one …

Abstract Supramolecular nanocapsule 1⋅(BArF) 8 is able to sequentially and selectively
entrap recently discovered U2@ C80 and unprecedented Sc2CU@ C80, simply by soaking …

Unsupported non-bridged uranium–carbon double bonds have long been sought after in
actinide chemistry as fundamental synthetic targets in the study of actinide-ligand multiple …

Dative bonds between p-and d-block atoms are common but species containing a double
dative bond, which donate two-electron pairs to the same acceptor, are far less common …

A series of actinide (An) species of L-An-N compounds [An= Pa–Pu, L=[N (CH2CH2NSiPri3)
3] 3–, Pri= CH (CH3) 2] have been investigated using scalar relativistic density functional …