The renaissance of non‐aqueous uranium chemistry
ST Liddle - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
USc2C2 and USc2NC Clusters with U–C Triple Bond Character Stabilized Inside Fullerene Cages
H Jiang, X Yu, M Guo, YR Yao, Q Meng… - Journal of the …, 2023 - ACS Publications
The chemistry of f-block metal–carbon multiple bonds is underdeveloped compared to well-
established carbene complexes of the d-block transition metals. Herein, we report two new …
established carbene complexes of the d-block transition metals. Herein, we report two new …
Metal–ligand multiple bonding in uranium: structure and reactivity
TW Hayton - Dalton Transactions, 2010 - pubs.rsc.org
There is a growing interest in uranium coordination chemistry, particularly as it relates to
metal–ligand multiple bonding, and in the last decade significant progress has been made …
metal–ligand multiple bonding, and in the last decade significant progress has been made …
Synthesis and characterization of U≡ C triple bonds in fullerene compounds
YR Yao, J Zhao, Q Meng, HS Hu, M Guo… - Journal of the …, 2023 - ACS Publications
Despite decades of efforts, the actinide–carbon triple bond has remained an elusive target,
defying synthesis in any isolable compound. Herein, we report the successful synthesis of …
defying synthesis in any isolable compound. Herein, we report the successful synthesis of …
Die Renaissance der nichtwässrigen Uranchemie
ST Liddle - Angewandte Chemie, 2015 - Wiley Online Library
Bis zum Jahr 2000 umfasste die nichtwässrige Uranchemie hauptsächlich Metallocen‐und
klassische Alkyl‐, Amid‐oder Alkoxidverbindungen sowie bekannte Carben‐, Imido‐und …
klassische Alkyl‐, Amid‐oder Alkoxidverbindungen sowie bekannte Carben‐, Imido‐und …
Relativistic quantum chemical calculations show that the uranium molecule U2 has a quadruple bond
Understanding the bonding, reactivity and electronic structure of actinides is lagging behind
that of the rest of the periodic table. This can be partly explained by the challenges that one …
that of the rest of the periodic table. This can be partly explained by the challenges that one …
Purification of uranium‐based endohedral metallofullerenes (EMFs) by selective supramolecular encapsulation and release
C Fuertes‐Espinosa, A Gómez‐Torres… - Angewandte …, 2018 - Wiley Online Library
Abstract Supramolecular nanocapsule 1⋅(BArF) 8 is able to sequentially and selectively
entrap recently discovered U2@ C80 and unprecedented Sc2CU@ C80, simply by soaking …
entrap recently discovered U2@ C80 and unprecedented Sc2CU@ C80, simply by soaking …
[HTML][HTML] A diuranium carbide cluster stabilized inside a C80 fullerene cage
Unsupported non-bridged uranium–carbon double bonds have long been sought after in
actinide chemistry as fundamental synthetic targets in the study of actinide-ligand multiple …
actinide chemistry as fundamental synthetic targets in the study of actinide-ligand multiple …
[HTML][HTML] Double dative bond between divalent carbon (0) and uranium
Dative bonds between p-and d-block atoms are common but species containing a double
dative bond, which donate two-electron pairs to the same acceptor, are far less common …
dative bond, which donate two-electron pairs to the same acceptor, are far less common …
Theoretical investigation on multiple bonds in terminal actinide nitride complexes
A series of actinide (An) species of L-An-N compounds [An= Pa–Pu, L=[N (CH2CH2NSiPri3)
3] 3–, Pri= CH (CH3) 2] have been investigated using scalar relativistic density functional …
3] 3–, Pri= CH (CH3) 2] have been investigated using scalar relativistic density functional …