Proton transport in metal–organic frameworks

DW Lim, H Kitagawa - Chemical reviews, 2020 - ACS Publications
Solid-state proton conductors (SSPCs), which are a key component for the safety and
efficiency of fuel cells, have received much attention due to their broad application in …

Classical and emerging characterization techniques for investigation of ion transport mechanisms in crystalline fast ionic conductors

Y Gao, AM Nolan, P Du, Y Wu, C Yang, Q Chen… - Chemical …, 2020 - ACS Publications
Ion transport in crystalline fast ionic conductors is a complex physical phenomenon. Certain
ionic species (eg, Ag+, Cu+, Li+, F–, O2–, H+) in a solid crystalline framework can move as …

Effect of dopant–host ionic radii mismatch on acceptor-doped barium zirconate microstructure and proton conductivity

E Gilardi, E Fabbri, L Bi, JLM Rupp… - The Journal of …, 2017 - ACS Publications
In the present study, morphological and electrical properties of BaZrO3 were investigated as
a function of the ionic radii mismatch between Zr and the different B-site dopants (Al, Sc, In …

Revealing the role of lattice distortions in the hydrogen-induced metal-insulator transition of SmNiO3

J Chen, W Mao, B Ge, J Wang, X Ke, V Wang… - Nature …, 2019 - nature.com
The discovery of hydrogen-induced electronic phase transitions in strongly correlated
materials such as rare-earth nickelates has opened up a new paradigm in regulating …

Enhanced Proton Conductivity in Y‐Doped BaZrO3 via Strain Engineering

A Fluri, A Marcolongo, V Roddatis, A Wokaun… - Advanced …, 2017 - Wiley Online Library
The effects of stress‐induced lattice distortions (strain) on the conductivity of Y‐doped
BaZrO3, a high‐temperature proton conductor with key technological applications for …

Li-ion diffusion in and battery materials detected by muon spin spectroscopy

J Sugiyama, H Nozaki, I Umegaki, K Mukai, K Miwa… - Physical Review B, 2015 - APS
Lithium diffusion in spinel Li 4 Ti 5 O 12 and LiTi 2 O 4 compounds for future battery
applications has been studied with muon spin relaxation (μ+ SR). Measurements were …

Experimental neutron scattering evidence for proton polaron in hydrated metal oxide proton conductors

A Braun, Q Chen - Nature communications, 2017 - nature.com
Hydration of oxygen-deficient metal oxides causes filling of oxygen vacancies and formation
of hydroxyl groups with interstitial structural protons, rotating around the oxygen in localized …

Surface strain and co-doping effect on Sm and Y co-doped BaCeO3 in proton conducting solid oxide fuel cells

L He, H Gao, Y Xuan, F Zhang, J Ren… - Computational Materials …, 2022 - Elsevier
Although promising, regulating the surface strain is still immature for enhance the
performance of proton-conducting materials and no clear law has been found. In this work …

Cooperative origin of proton pair diffusivity in yttrium substituted barium zirconate

P Du, Q Chen, Z Fan, H Pan, FG Haibach… - Communications …, 2020 - nature.com
Proton conduction is an important property for fuel cell electrolytes. The search for molecular
details on proton transport is an ongoing quest. Here, we show that in hydrated yttrium …

Conductivity study of dense BaZr0. 9Y0. 1O (3− δ) obtained by spark plasma sintering

S Ricote, N Bonanos, HJ Wang, BA Boukamp - Solid State Ionics, 2012 - Elsevier
10% yttrium doped barium zirconate (BZY10) was synthesized by solid state reaction and a
99.8% dense and transparent sample was prepared by spark plasma sintering (SPS) at …