Coordination versatility of NHC-metal topologies in asymmetric catalysis: Synthetic insights and recent trends
A Jayaraj, AV Raveedran, AT Latha… - Coordination Chemistry …, 2023 - Elsevier
Asymmetric metal based catalysis has advanced quickly in recent years, with its efficiency
relying exclusively on chiral ligands. Rational design and meticulous selection of chiral …
relying exclusively on chiral ligands. Rational design and meticulous selection of chiral …
Bidentate Donor-Functionalized N-Heterocyclic Carbenes: Valuable Ligands for Ruthenium-Catalyzed Transfer Hydrogenation
Ruthenium complexes are by far the most studied compounds that catalyze hydrogen
transfer reactions. In this review, we describe the use in this field of ruthenium complexes …
transfer reactions. In this review, we describe the use in this field of ruthenium complexes …
Insights into microwave‐promoted synthesis of 3‐methyl‐4‐phenyl‐4, 9‐dihydro‐1H‐pyrazolo [3, 4‐d][1, 2, 4] triazolo [1, 5‐a] pyrimidine derivatives catalyzed using …
MAEAA Ali El‐Remaily, MSH Alzubi… - Applied …, 2024 - Wiley Online Library
Four novel Pd (II), Cu (II), VO (II), and Ag (I) complexes were prepared from benzimidazole
ligand through bidentate chelating mode. Alternative spectral and analytical tools were …
ligand through bidentate chelating mode. Alternative spectral and analytical tools were …
Rh (I) complexes with hemilabile thioether-functionalized NHC ligands as catalysts for [2+ 2+ 2] cycloaddition of 1, 5-bisallenes and alkynes
J Vila, M Solà, T Achard, S Bellemin-Laponnaz… - ACS …, 2023 - ACS Publications
The [2+ 2+ 2] cycloaddition of 1, 5-bisallenes and alkynes under the catalysis of Rh (I) with
hemilabile thioether-functionalized N-heterocyclic carbene ligands is described. This …
hemilabile thioether-functionalized N-heterocyclic carbene ligands is described. This …
MCM-41 supported 2-aminothiophenol/Cu complex as a sustainable nanocatalyst for Suzuki coupling reaction
S Bibak, A Poursattar Marjani… - Scientific Reports, 2024 - nature.com
We have developed an innovative mesoporous nanocatalyst by carefully attaching a 2-
aminothiophenol-Cu complex onto functionalized MCM-41. This straightforward synthesis …
aminothiophenol-Cu complex onto functionalized MCM-41. This straightforward synthesis …
Palladium, iridium, and rhodium complexes bearing chiral N‐heterocyclic carbene ligands applied in asymmetric catalysis
N Mukherjee, B Mondal, TN Saha… - Applied Organometallic …, 2024 - Wiley Online Library
The field of asymmetric catalysis is rapidly developing and the chiral ligands play a key role
in enantioselective transition‐metal catalysis. The electron‐rich chiral N‐heterocyclic …
in enantioselective transition‐metal catalysis. The electron‐rich chiral N‐heterocyclic …
A Review on Generation and Reactivity of the N-Heterocyclic Carbene-Bound Alkynyl Acyl Azolium Intermediates
Z Dong, C Jiang, C Zhao - Molecules, 2022 - mdpi.com
N-heterocyclic carbene (NHC) has been widely used as an organocatalyst for both
umpolung and non-umpolung chemistry. Previous works mainly focus on species including …
umpolung and non-umpolung chemistry. Previous works mainly focus on species including …
Recent Advances in the Titanium-Based Catalysts for Ring-Opening Polymerization
W Wang - ACS omega, 2024 - ACS Publications
At present, economic development and daily life cannot be separated from organic synthetic
polymers. However, a large number of nondegradable polymers have caused serious …
polymers. However, a large number of nondegradable polymers have caused serious …
Diaza-1, 3-butadienes as useful intermediate in heterocycles synthesis
J Heredia-Moya, DA Zurita, JE Cadena-Cruz… - Molecules, 2022 - mdpi.com
Many heterocyclic compounds can be synthetized using diaza-1, 3-butadienes (DADs) as
key structural precursors. Isolated and in situ diaza-1, 3-butadienes, produced from their …
key structural precursors. Isolated and in situ diaza-1, 3-butadienes, produced from their …
Impact of Ligand Modification on the Hydrogen Evolution Reaction of Highly Active Silver (I)-and Ruthenium (II)-N-Heterocyclic Carbene-Based Electrocatalysts …
The development of efficient small-molecule electrocatalysts for the hydrogen evolution
reaction (HER) is crucial in advanced water splitting and fuel cell applications. The use of …
reaction (HER) is crucial in advanced water splitting and fuel cell applications. The use of …