Enzymatic halogenation and dehalogenation reactions: pervasive and mechanistically diverse
Naturally produced halogenated compounds are ubiquitous across all domains of life where
they perform a multitude of biological functions and adopt a diversity of chemical structures …
they perform a multitude of biological functions and adopt a diversity of chemical structures …
[HTML][HTML] Biosynthesis of the modified tetrapyrroles—the pigments of life
Modified tetrapyrroles are large macrocyclic compounds, consisting of diverse conjugation
and metal chelation systems and imparting an array of colors to the biological structures that …
and metal chelation systems and imparting an array of colors to the biological structures that …
[HTML][HTML] Feed additives as a strategic approach to reduce enteric methane production in cattle: modes of action, effectiveness and safety
Increasing consumer concern in greenhouse-gas (GHG) contributions from cattle is pushing
the livestock industry to continue to improve their sustainability goals. As populations …
the livestock industry to continue to improve their sustainability goals. As populations …
Mixed quantum mechanical/molecular mechanical molecular dynamics simulations of biological systems in ground and electronically excited states
E Brunk, U Rothlisberger - Chemical reviews, 2015 - ACS Publications
The quantum nature of electrons and nuclei is manifested in countless biological events
including the rearrangements of electrons in biochemical reactions, electron and proton …
including the rearrangements of electrons in biochemical reactions, electron and proton …
[HTML][HTML] The requirement for cobalt in vitamin B12: A paradigm for protein metalation
Vitamin B 12, cobalamin, is a cobalt-containing ring-contracted modified tetrapyrrole that
represents one of the most complex small molecules made by nature. In prokaryotes it is …
represents one of the most complex small molecules made by nature. In prokaryotes it is …
[HTML][HTML] Energy conservation via electron bifurcating ferredoxin reduction and proton/Na+ translocating ferredoxin oxidation
W Buckel, RK Thauer - Biochimica et Biophysica Acta (BBA)-Bioenergetics, 2013 - Elsevier
The review describes four flavin-containing cytoplasmatic multienzyme complexes from
anaerobic bacteria and archaea that catalyze the reduction of the low potential ferredoxin by …
anaerobic bacteria and archaea that catalyze the reduction of the low potential ferredoxin by …
Interactive tree of life (iTOL) v3: an online tool for the display and annotation of phylogenetic and other trees
Abstract Interactive Tree Of Life (http://itol. embl. de) is a web-based tool for the display,
manipulation and annotation of phylogenetic trees. It is freely available and open to …
manipulation and annotation of phylogenetic trees. It is freely available and open to …
[HTML][HTML] Antimicrobial transformation products in the aquatic environment: global occurrence, ecotoxicological risks, and potential of antibiotic resistance
The global spread of antimicrobial resistance (AMR) is concerning for the health of humans,
animals, and the environment in a One Health perspective. Assessments of AMR and …
animals, and the environment in a One Health perspective. Assessments of AMR and …
Prokaryotic heme biosynthesis: multiple pathways to a common essential product
The advent of heme during evolution allowed organisms possessing this compound to
safely and efficiently carry out a variety of chemical reactions that otherwise were difficult or …
safely and efficiently carry out a variety of chemical reactions that otherwise were difficult or …
Biocatalytic reduction reactions from a chemist's perspective
F Hollmann, DJ Opperman… - Angewandte Chemie …, 2021 - Wiley Online Library
Reductions play a key role in organic synthesis, producing chiral products with new
functionalities. Enzymes can catalyse such reactions with exquisite stereo‐, regio‐and …
functionalities. Enzymes can catalyse such reactions with exquisite stereo‐, regio‐and …