Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Metal carbonyl clusters of groups 8–10: synthesis and catalysis

C Cesari, JH Shon, S Zacchini… - Chemical Society Reviews, 2021 - pubs.rsc.org
In this review article, we discuss advances in the chemistry of metal carbonyl clusters
(MCCs) spanning the last three decades, with an emphasis on the more recent reports and …

Doubly mononuclear cocrystal and oxalato-bridged binuclear copper compounds containing flexible 2-((3, 5, 6-trichloropyridin-2-yl) oxy) acetate tectons: Synthesis …

JX Li, ZX Du, LL Zhang, DL Liu, QY Pan - Inorganica Chimica Acta, 2020 - Elsevier
Two new copper compounds, namely [Cu (3, 5, 6-tcpa) 2 (H 2 O) 4]·[Cu (3, 5, 6-tcpa) 2 (H 2
O) 2](1) and [Cu 2 (3, 5, 6-tcpa) 2 (2, 2′-bipy) 2 (oxa)]· 2EtOH (2)(3, 5, 6-Htcpa= 2-((3, 5, 6 …

Deep oxidative desulfurization of model fuels catalyzed by subnanosized Ti oxoclusters

T Zhang, X Chen, B Ding, Z Ding, Y Wang, H Qiu… - Energy & …, 2022 - ACS Publications
Oxidative desulfurization is a highly effective approach to decrease the sulfur content in
transportation fuel and has become an attractive research topic in recent years. Herewith …

Insight into the formation of bismuth-tungsten carbonyl clusters

K Beuthert, B Peerless, S Dehnen - Communications Chemistry, 2023 - nature.com
Multimetallic clusters play a key role as models to doped metals, as candidates to new types
of superatomic catalysts and as precursors to new multimetallic solids. Understanding …

Base-Free Catalytic Hydrogen Production from Formic Acid Mediated by a Cubane-Type Mo3S4 Cluster Hydride

E Guillamón, I Sorribes, VS Safont, AG Algarra… - Inorganic …, 2022 - ACS Publications
Formic acid (FA) dehydrogenation is an attractive process in the implementation of a
hydrogen economy. To make this process greener and less costly, the interest nowadays is …

[HTML][HTML] Molecular hydride carbonyl clusters and nanoclusters

C Cesari, C Femoni, F Forti, MC Iapalucci… - Inorganica Chimica …, 2024 - Elsevier
This minireview outlines the actual status of the chemistry of hydride metal carbonyl clusters
(MCCs) by means of pertinent examples, without being comprehensive. After a brief …

Syntheses and Properties of Triruthenium Polyhydrido Complexes Composed of 1,2,4-tri-tert-butylcyclopentadienyl and p-Cymene Ruthenium Units

T Takao, H Suzuki, R Shimogawa - Organometallics, 2021 - ACS Publications
Mixed-ligand triruthenium hydrido complexes composed of [Cp‡ Ru](Cp‡= 1, 2, 4-tri-tert-
butylcyclopentadienyl) and [(p-cymene) Ru] fragments,[(Cp‡ Ru) 2 {(p-cymene) Ru}(μ-H) 3 …

Electronic structure study of clusters containing Fe-Fe transition metal ions: QTAIM approach

MAM Al-Jabery, SRH Alhimidi… - AIP Conference …, 2023 - pubs.aip.org
The topological indices of the [Fe3 (C3H6N2)(μ3-S) 2 (CO) 8] is studied within the quantum
theory of atoms in the molecule (QTAIM) and analysed using the density functional theory …

Into the Role of Unsaturated Trinuclear Metal Carbonyls in the Formation of [M3(2,3-bpp)(CO)10] with M=Ru, Os: A DFT Stability Analysis and Electronic Structure

K Paredes-Gil, E Galarza, JY Aguilar-Hurtado… - Journal of Cluster …, 2023 - Springer
The metal carbonyl clusters have been recognized as one of the most successful
organometallic complexes with extensive catalytic applications. In this paper, we carried out …