Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach
C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …
Radical ring-opening polymerization: Scope, limitations, and application to (bio) degradable materials
A Tardy, J Nicolas, D Gigmes, C Lefay… - Chemical …, 2017 - ACS Publications
Cyclic monomers bearing either vinyl or exomethylene groups have the ability to be
polymerized through a radical pathway via a ring-opening mechanism (addition …
polymerized through a radical pathway via a ring-opening mechanism (addition …
Ring-opening polymerization—an introductory review
O Nuyken, SD Pask - Polymers, 2013 - mdpi.com
This short, introductory review covers the still rapidly growing and industrially important field
of ring opening polymerization (ROP). The review is organized according to mechanism …
of ring opening polymerization (ROP). The review is organized according to mechanism …
Current Standing on Radical Ring‐Opening Polymerizations of Cyclic Ketene Acetals as Homopolymers and Copolymers with one another
Radical Ring‐opening polymerization (RROP) of cyclic ketene acetals (CKAs) emerges to
be a valuable polymerization technique. In attracting more attention, RROP has seen a new …
be a valuable polymerization technique. In attracting more attention, RROP has seen a new …
PVA free-radical diblock copolymer for nanoencapsulation with enhanced biodegradability in the environment
SR Mothe, P Kanaujia, ABY Oh, P Ang… - European Polymer …, 2023 - Elsevier
The synthesis of readily biodegradable amphiphilic polyvinyl alcohol diblock copolymers
(poly (VA-b-MDO)) was achieved through the combination of radical ring-opening …
(poly (VA-b-MDO)) was achieved through the combination of radical ring-opening …
Reversible-deactivation radical polymerization of cyclic ketene acetals
AW Jackson - Polymer Chemistry, 2020 - pubs.rsc.org
While synthetic polymers have found widespread application in personal and consumer
care, and agrochemical and biomedical applications, there remains a constant drive to …
care, and agrochemical and biomedical applications, there remains a constant drive to …
Vinyl copolymers with faster hydrolytic degradation than aliphatic polyesters and tunable upper critical solution temperatures
A Bossion, C Zhu, L Guerassimoff, J Mougin… - Nature …, 2022 - nature.com
Vinyl polymers are the focus of intensive research due to their ease of synthesis and the
possibility of making well-defined, functional materials. However, their non-degradability …
possibility of making well-defined, functional materials. However, their non-degradability …
Mechanism-Guided Discovery of Cleavable Comonomers for Backbone Deconstructable Poly (methyl methacrylate)
The development of cleavable comonomers (CCs) with suitable copolymerization reactivity
paves the way for the introduction of backbone deconstructability into polymers. Recent …
paves the way for the introduction of backbone deconstructability into polymers. Recent …
Molecular bionics–engineering biomaterials at the molecular level using biological principles
Life and biological units are the result of the supramolecular arrangement of many different
types of molecules, all of them combined with exquisite precision to achieve specific …
types of molecules, all of them combined with exquisite precision to achieve specific …
pH-labile and photochemically cross-linkable polymer vesicles from coumarin based random copolymer for cancer therapy
The stability of a drug payload inside a nanocarrier at physiological environment and the
release of the said drug at specific tumor cells in a sustainable manner are the two most …
release of the said drug at specific tumor cells in a sustainable manner are the two most …