Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach

C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …

Radical ring-opening polymerization: Scope, limitations, and application to (bio) degradable materials

A Tardy, J Nicolas, D Gigmes, C Lefay… - Chemical …, 2017 - ACS Publications
Cyclic monomers bearing either vinyl or exomethylene groups have the ability to be
polymerized through a radical pathway via a ring-opening mechanism (addition …

Ring-opening polymerization—an introductory review

O Nuyken, SD Pask - Polymers, 2013 - mdpi.com
This short, introductory review covers the still rapidly growing and industrially important field
of ring opening polymerization (ROP). The review is organized according to mechanism …

Current Standing on Radical Ring‐Opening Polymerizations of Cyclic Ketene Acetals as Homopolymers and Copolymers with one another

Y Deng, F Mehner, J Gaitzsch - Macromolecular Rapid …, 2023 - Wiley Online Library
Radical Ring‐opening polymerization (RROP) of cyclic ketene acetals (CKAs) emerges to
be a valuable polymerization technique. In attracting more attention, RROP has seen a new …

PVA free-radical diblock copolymer for nanoencapsulation with enhanced biodegradability in the environment

SR Mothe, P Kanaujia, ABY Oh, P Ang… - European Polymer …, 2023 - Elsevier
The synthesis of readily biodegradable amphiphilic polyvinyl alcohol diblock copolymers
(poly (VA-b-MDO)) was achieved through the combination of radical ring-opening …

Reversible-deactivation radical polymerization of cyclic ketene acetals

AW Jackson - Polymer Chemistry, 2020 - pubs.rsc.org
While synthetic polymers have found widespread application in personal and consumer
care, and agrochemical and biomedical applications, there remains a constant drive to …

Vinyl copolymers with faster hydrolytic degradation than aliphatic polyesters and tunable upper critical solution temperatures

A Bossion, C Zhu, L Guerassimoff, J Mougin… - Nature …, 2022 - nature.com
Vinyl polymers are the focus of intensive research due to their ease of synthesis and the
possibility of making well-defined, functional materials. However, their non-degradability …

Mechanism-Guided Discovery of Cleavable Comonomers for Backbone Deconstructable Poly (methyl methacrylate)

K Ko, DJ Lundberg, AM Johnson… - Journal of the American …, 2024 - ACS Publications
The development of cleavable comonomers (CCs) with suitable copolymerization reactivity
paves the way for the introduction of backbone deconstructability into polymers. Recent …

Molecular bionics–engineering biomaterials at the molecular level using biological principles

L Rodríguez-Arco, A Poma, L Ruiz-Pérez, E Scarpa… - Biomaterials, 2019 - Elsevier
Life and biological units are the result of the supramolecular arrangement of many different
types of molecules, all of them combined with exquisite precision to achieve specific …

pH-labile and photochemically cross-linkable polymer vesicles from coumarin based random copolymer for cancer therapy

P Samanta, K Kapat, S Maiti, G Biswas, S Dhara… - Journal of colloid and …, 2019 - Elsevier
The stability of a drug payload inside a nanocarrier at physiological environment and the
release of the said drug at specific tumor cells in a sustainable manner are the two most …