Explorations of the indenofluorenes and expanded quinoidal analogues

CK Frederickson, BD Rose… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus Highly conjugated hydrocarbons have attracted interest for use as active
materials in electronic devices such as organic field effect transistors (OFET) and organic …

Breathing new life into nonalternant hydrocarbon chemistry: Syntheses and properties of polycyclic hydrocarbons containing azulene, pentalene, and heptalene …

A Konishi, M Yasuda - Chemistry Letters, 2021 - academic.oup.com
Abstract Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons.
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …

Tetra‐tert‐butyl‐s‐indacene is a Bond‐Localized C2h Structure and a Challenge for Computational Chemistry

LJ Karas, S Jalife, RV Viesser… - Angewandte Chemie …, 2023 - Wiley Online Library
Whether tetra‐tert‐butyl‐s‐indacene is a symmetric D2h structure or a bond‐alternating C2h
structure remains a standing puzzle. Close agreement between experimental and computed …

Dinor [7] helicene and Beyond: Divergent Synthesis of Chiral Diradicaloids with Variable Open‐Shell Character

A Borissov, PJ Chmielewski… - Angewandte Chemie …, 2023 - Wiley Online Library
Diradicaloid helicenes constructed formally by non‐benzenoid double π‐extension of
phenanthrene were synthesized by a common strategy involving double electrophilic …

Learning how to fine‐tune diradical properties by structure refinement

JJ Dressler, MM Haley - Journal of Physical Organic Chemistry, 2020 - Wiley Online Library
The literature has seen a large increase in the number of new carbon‐based organic
diradicals/diradicaloids in recent years. While a plethora of new and exciting structures have …

Recent Progress in High Linearly Fused Polycyclic Conjugated Hydrocarbons (PCHs, n > 6) with Well‐Defined Structures

W Chen, F Yu, Q Xu, G Zhou, Q Zhang - Advanced Science, 2020 - Wiley Online Library
Although polycyclic conjugated hydrocarbons (PCHs) and their analogues have gained
great progress in the fields of organic photoelectronic materials, the in‐depth study on …

Open-shell and antiaromatic character induced by the highly symmetric geometry of the planar heptalene structure: synthesis and characterization of a nonalternant …

A Konishi, K Horii, D Shiomi, K Sato… - Journal of the …, 2019 - ACS Publications
A nonbenzenoid hydrocarbon, difluoreno [1, 9, 8-alkj: 1′, 9′, 8′-gfed] heptalene 1, is
synthesized. Experimental and theoretical investigations demonstrate that the planar and …

Engineering the HOMO–LUMO gap of indeno [1, 2-b] fluorene

R Casares, Á Martínez-Pinel… - Journal of Materials …, 2022 - pubs.rsc.org
A direct, efficient and versatile strategy for the modulation of optoelectronic and magnetic
properties of indeno [1, 2-b] fluorene has been developed. 4-Substituted-2, 6 …

Generating antiaromaticity in polycyclic conjugated hydrocarbons by thermally selective skeletal rearrangements at interfaces

E Pérez-Elvira, A Barragán, Q Chen, D Soler-Polo… - Nature …, 2023 - nature.com
Antiaromatic polycyclic conjugated hydrocarbons (PCHs) are attractive research targets
because of their interesting structural, electronic and magnetic properties. Unlike aromatic …

Synthesis of the Unknown Indeno[1,2‐a]fluorene Regioisomer: Crystallographic Characterization of Its Dianion

JJ Dressler, Z Zhou, JL Marshall, R Kishi… - Angewandte …, 2017 - Wiley Online Library
Of the five possible indenofluorene regioisomers, examples of a fully conjugated indeno [1,
2‐a] fluorene scaffold have so far remained elusive. This work reports the preparation and …