Explorations of the indenofluorenes and expanded quinoidal analogues
CK Frederickson, BD Rose… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus Highly conjugated hydrocarbons have attracted interest for use as active
materials in electronic devices such as organic field effect transistors (OFET) and organic …
materials in electronic devices such as organic field effect transistors (OFET) and organic …
Breathing new life into nonalternant hydrocarbon chemistry: Syntheses and properties of polycyclic hydrocarbons containing azulene, pentalene, and heptalene …
A Konishi, M Yasuda - Chemistry Letters, 2021 - academic.oup.com
Abstract Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons.
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …
Tetra‐tert‐butyl‐s‐indacene is a Bond‐Localized C2h Structure and a Challenge for Computational Chemistry
Whether tetra‐tert‐butyl‐s‐indacene is a symmetric D2h structure or a bond‐alternating C2h
structure remains a standing puzzle. Close agreement between experimental and computed …
structure remains a standing puzzle. Close agreement between experimental and computed …
Dinor [7] helicene and Beyond: Divergent Synthesis of Chiral Diradicaloids with Variable Open‐Shell Character
A Borissov, PJ Chmielewski… - Angewandte Chemie …, 2023 - Wiley Online Library
Diradicaloid helicenes constructed formally by non‐benzenoid double π‐extension of
phenanthrene were synthesized by a common strategy involving double electrophilic …
phenanthrene were synthesized by a common strategy involving double electrophilic …
Learning how to fine‐tune diradical properties by structure refinement
JJ Dressler, MM Haley - Journal of Physical Organic Chemistry, 2020 - Wiley Online Library
The literature has seen a large increase in the number of new carbon‐based organic
diradicals/diradicaloids in recent years. While a plethora of new and exciting structures have …
diradicals/diradicaloids in recent years. While a plethora of new and exciting structures have …
Recent Progress in High Linearly Fused Polycyclic Conjugated Hydrocarbons (PCHs, n > 6) with Well‐Defined Structures
Although polycyclic conjugated hydrocarbons (PCHs) and their analogues have gained
great progress in the fields of organic photoelectronic materials, the in‐depth study on …
great progress in the fields of organic photoelectronic materials, the in‐depth study on …
Open-shell and antiaromatic character induced by the highly symmetric geometry of the planar heptalene structure: synthesis and characterization of a nonalternant …
A nonbenzenoid hydrocarbon, difluoreno [1, 9, 8-alkj: 1′, 9′, 8′-gfed] heptalene 1, is
synthesized. Experimental and theoretical investigations demonstrate that the planar and …
synthesized. Experimental and theoretical investigations demonstrate that the planar and …
Engineering the HOMO–LUMO gap of indeno [1, 2-b] fluorene
R Casares, Á Martínez-Pinel… - Journal of Materials …, 2022 - pubs.rsc.org
A direct, efficient and versatile strategy for the modulation of optoelectronic and magnetic
properties of indeno [1, 2-b] fluorene has been developed. 4-Substituted-2, 6 …
properties of indeno [1, 2-b] fluorene has been developed. 4-Substituted-2, 6 …
Generating antiaromaticity in polycyclic conjugated hydrocarbons by thermally selective skeletal rearrangements at interfaces
Antiaromatic polycyclic conjugated hydrocarbons (PCHs) are attractive research targets
because of their interesting structural, electronic and magnetic properties. Unlike aromatic …
because of their interesting structural, electronic and magnetic properties. Unlike aromatic …
Synthesis of the Unknown Indeno[1,2‐a]fluorene Regioisomer: Crystallographic Characterization of Its Dianion
Of the five possible indenofluorene regioisomers, examples of a fully conjugated indeno [1,
2‐a] fluorene scaffold have so far remained elusive. This work reports the preparation and …
2‐a] fluorene scaffold have so far remained elusive. This work reports the preparation and …