The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Rapidly emerging application of organometallic manganese complexes incorporating less
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …

Recent developments in manganese-catalyzed reducing transformations—hydrosilylation,
hydroboration, hydrogenation, and transfer hydrogenation—are reviewed herein. Over the …

Highlights•Mn complexes can catalyze transfer hydrogenation of C double bond O, C double
bond N, C double bond C, C triple bond N, and C triple bond C bonds.•Mn-catalyzed transfer …

Chiral oxazolidinones are a class of important heterocyclic compounds in pharmaceutical
chemistry due to their biological activity. Halohydrin dehalogenase-catalyzed epoxide ring …

Controlling the selectivity in a hydroamination reaction is an extremely challenging yet
highly desirable task for the diversification of amines. In this article, a selective formal anti …

A series of manganese (I) carbonyl complexes bearing structurally related NN-and NNN-
chelating ligands have been synthesized and assessed as catalysts for transfer …

Chemoselective transfer hydrogenation of C= C bond in α, β‐unsaturated ketones is
demonstrated at room temperature employing a manganese (I) catalyst and half an …

A series of commercially available chiral amino-phosphines, in combination with Mn (CO) 5
Br, has been evaluated for the asymmetric reduction of ketones, using isopropanol as …

Catalysts for transfer hydrogenation (TH) reactions based on the earth abundant transition
metal manganese are an emerging field of research. A common moiety found in most …