Syntheses of gem-Dihalocyclopropanes and Their Use in Organic Synthesis

M Fedoryński - Chemical reviews, 2003 - ACS Publications
I. Introduction gem-Dihalocyclopropanes play an important role in organic synthesis. They
are valuable substrates for the preparation of monohalocyclopropanes, cyclopropanes …

Amaryllidaceae and Sceletium alkaloids

Z Jin - Natural product reports, 2003 - pubs.rsc.org
Covering: July 2001 to December 2002. Previous review: Nat. Prod. Rep., 2002, 19, 454This
review covers the isolation, biological activity and chemical synthesis of Amaryllidaceae …

Development of an intramolecular aryne ene reaction and application to the formal synthesis of (±)-crinine

DA Candito, D Dobrovolsky… - Journal of the American …, 2012 - ACS Publications
A general and high yielding annulation strategy for the synthesis of various carbo-and
heterocycles, based on an intramolecular aryne ene reaction is described. It was found that …

Total syntheses of lyconadins A–C

T Nishimura, AK Unni, S Yokoshima… - Journal of the …, 2013 - ACS Publications
The total synthesis of the Lycopodium alkaloid lyconadin A was accomplished and it was
applied to the total syntheses of the related congeners, lyconadins B and C. Lyconadin A …

Bioactive Phytochemicals: Bioactivity, Sources, Preparations, and/or Modifications via Silver Tetrafluoroborate Mediation

MC Achilonu, DO Umesiobi - Journal of Chemistry, 2015 - Wiley Online Library
This review provides an overview of the biological activities, natural occurrences, and the
silver tetrafluoroborate‐(AgBF4‐) mediated synthesis of proanthocyanidins, glycosides, N …

Silver-assisted Syntheses of Fused Five-membered N-heterocycles

N Kaur, N Ahlawat, Y Verma, P Grewal… - Current Organic …, 2021 - ingentaconnect.com
The metal-mediated formation of heterocycles is one of the most emerging and important
strategies in organic chemistry. The reactions utilized previously for the synthesis of …

New protocols for the assembly of the tetracyclic framework associated with the aromatic erythrina alkaloids

PC Stanislawski, AC Willis, MG Banwell - Organic Letters, 2006 - ACS Publications
Treatment of the anion derived from the ring-fused gem-dichlorocyclopropane 4c with silver
tetrafluoroborate afforded the spirocyclic compound 17 in 74% yield. Product 17 was readily …

gem‐Dihalocyclopropanes as Building Blocks in Natural‐Product Synthesis: Enantioselective Total Syntheses of ent‐Erythramine and 3‐epi‐Erythramine

PC Stanislawski, AC Willis… - Chemistry–An Asian …, 2007 - Wiley Online Library
Abstract ent‐Erythramine ((−)‐1), the enantiomer of the alkaloid erythramine, was prepared
in 15 steps from known compounds. The first of three pivotal bond‐forming steps in the …

Pyrroles and gem-dihalocyclopropanes as building blocks for alkaloid synthesis

MG Banwell, DAS Beck, PC Stanislawski… - Current Organic …, 2005 - ingentaconnect.com
Pyrroles and gem-dihalocyclopropanes are both readily accessible classes of compound.
They have considerable potential as building blocks in the construction of alkaloid …

The chemical synthesis of the crinine and haemanthamine alkaloids: biologically active and enantiomerically-related systems that serve as vehicles for showcasing …

N Hu, LV White, P Lan, MG Banwell - Molecules, 2021 - mdpi.com
The title alkaloids, often referred to collectively as crinines, are a prominent group of
structurally distinct natural products with additional members being reported on a regular …