Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Organic synthesis using nitroxides
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
Ferrocene-Mediated Photocatalytic Annulation of N-Sulfonyl Ketimines on a Polycrystalline WSe2 Semiconductor Photocatalyst
YH Lu, C Wu, JC Hou, ZL Wu, MH Zhou, XJ Huang… - ACS …, 2023 - ACS Publications
A merger of heterogeneous polycrystalline WSe2 semiconductor photocatalysis and
homogeneous ferrocene redox catalysis for the cascade radical coupling-annulation …
homogeneous ferrocene redox catalysis for the cascade radical coupling-annulation …
Recent advances in organic electrosynthesis employing transition metal complexes as electrocatalysts
C Ma, P Fang, ZR Liu, SS Xu, K Xu, X Cheng, A Lei… - Science Bulletin, 2021 - Elsevier
Organic electrosynthesis has been widely used as an environmentally conscious alternative
to conventional methods for redox reactions because it utilizes electric current as a traceless …
to conventional methods for redox reactions because it utilizes electric current as a traceless …
Electrode materials in modern organic electrochemistry
DM Heard, AJJ Lennox - Angewandte Chemie International …, 2020 - Wiley Online Library
The choice of electrode material is critical for achieving optimal yields and selectivity in
synthetic organic electrochemistry. The material imparts significant influence on the kinetics …
synthetic organic electrochemistry. The material imparts significant influence on the kinetics …
Electrochemical oxidation of organic molecules at lower overpotential: Accessing broader functional group compatibility with electron− proton transfer mediators
F Wang, SS Stahl - Accounts of chemical research, 2020 - ACS Publications
Conspectus Electrochemical organic oxidation reactions are highly appealing because
protons are often effective terminal electron acceptors, thereby avoiding undesirable …
protons are often effective terminal electron acceptors, thereby avoiding undesirable …
Electrochemical strategies for C–H functionalization and C–N bond formation
MD Kärkäs - Chemical Society Reviews, 2018 - pubs.rsc.org
Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …
An electrocatalytic approach to the radical difunctionalization of alkenes
Given its many distinct characteristics, electrochemistry represents an attractive approach to
meet the prevailing trends in organic synthesis. In particular, electrocatalysis—a process that …
meet the prevailing trends in organic synthesis. In particular, electrocatalysis—a process that …
Ferrocene‐based metal–organic framework nanosheets as a robust oxygen evolution catalyst
J Liang, X Gao, B Guo, Y Ding, J Yan… - Angewandte Chemie …, 2021 - Wiley Online Library
We report the synthesis of two‐dimensional metal–organic frameworks (MOFs) on nickel
foam (NF) by assembling nickel chloride hexahydrate and 1, 1′‐ferrocenedicarboxylic acid …
foam (NF) by assembling nickel chloride hexahydrate and 1, 1′‐ferrocenedicarboxylic acid …
Microfluidic electrochemistry for single-electron transfer redox-neutral reactions
Electrochemistry offers opportunities to promote single-electron transfer (SET) redox-neutral
chemistries similar to those recently discovered using visible-light photocatalysis but without …
chemistries similar to those recently discovered using visible-light photocatalysis but without …