Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded
as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes …

The carboxylate ligand,[RCO 2]−, is one of the most versatile and hence also one of the most
ubiquitous ligands in coordination chemistry.(1-4) Although fairly simple coordination modes …

The synthesis, structures, and magnetic properties of six families of cobalt–lanthanide mixed-
metal phosphonate complexes are reported in this Article. These six families can be divided …

Magnetic refrigeration is based on the magnetocaloric effect (MCE) which relies on the
entropy change of a material when placed in a magnetic field. 1 Molecular magnets have …

Three 3d–4f phosphonate complexes,[CoII8GdIII8 (μ3-OH) 4 (NO3) 4 (O3PtBu) 8 (O2CtBu)
16],[CoII8GdIII4 (O3PtBu) 6 (O2CtBu) 16] and [CoII4GdIII6 (O3PCH2Ph) 6 (O2CtBu) 14 …

Two neutral silver (I)− phenylethynide clusters incorporating the [(t BuPO3) 4V4O8] 4− unit
as an integral shell component, namely {(NO3) 2@ Ag16 (C CPh) 4 [(t BuPO3) 4V4O8] 2 …

3d –4f Clusters with large spin ground states and SMM behaviour - Dalton Transactions (RSC
Publishing) DOI:10.1039/B927114G Royal Society of Chemistry View PDF VersionPrevious …

Functionalization of polyoxovanadate clusters using phosphonate and arsonate ligands
results in molecular capsules (see structure; green V, purple P, red O, black C). Through the …

Giant mixed‐metal clusters have been assembled with the multinuclear silver (I) tert‐
butylethynide supramolecular synthon and phosphonate‐functionalized oxovanadate …

Supramolecular coordination cages provide unique restricted inner cavities that can be
exploited for molecular recognition purposes and catalysis. Their syntheses often involve …