From theory to practice: leveraging chemical principles to improve the performance of peroxydisulfate-based in situ chemical oxidation of organic contaminants

L McGachy, DL Sedlak - Environmental Science & Technology, 2023 - ACS Publications
In situ chemical oxidation (ISCO) using peroxydisulfate has become more popular in the
remediation of soils and shallow groundwater contaminated with organic chemicals …

Reduction potentials involving inorganic free radicals in aqueous solution

DM Stanbury - Advances in inorganic chemistry, 1989 - Elsevier
Publisher Summary This chapter discusses the reduction potentials involving inorganic free
radicals in aqueous solution. Because free radicals are usually transients, knowing their …

Entry of free radicals into latex particles in emulsion polymerization

IA Maxwell, BR Morrison, DH Napper… - Macromolecules, 1991 - ACS Publications
A model, together with a comparison with previously published experimental data, is
presented for initiator efficiency in seeded styreneemulsion polymerization systems in the …

[PDF][PDF] Novel activation technologies for sodium persulfate in situ chemical oxidation

PA Block, RA Brown, D Robinson - Proceedings of the Fourth …, 2004 - projects.battelle.org
Persulfate oxidation chemistry is an emerging technology for the in situ chemical oxidation of
chlorinated and non-chlorinated organics. Activation of persulfate to form sulfate radicals is a …

Identification of produced powerful radicals involved in the mineralization of bisphenol A using a novel UV-Na2S2O8/H2O2-Fe (II, III) two-stage oxidation process

YF Huang, YH Huang - Journal of Hazardous Materials, 2009 - Elsevier
A two-stage oxidation (UV-Na2S2O8/H2O2-Fe (II, III)) process was applied to mineralize
bisphenol A (BPA) at pHi (initial pH) 7. We take advantage of the high oxidation potential of …

Emulsion Polymerization of n-Butyl Methacrylate by Reverse Atom Transfer Radical Polymerization

J Qiu, SG Gaynor, K Matyjaszewski - Macromolecules, 1999 - ACS Publications
The controlled/“living” radical polymerization of n-butyl methacrylate was conducted in an
emulsion under reverse atom transfer radical polymerization (ATRP) conditions. The …

Recent advances in f-element separations based on a new method for the production of pentavalent americium in acidic solution

BJ Mincher, NC Schmitt, BK Schuetz, TC Shehee… - RSC Advances, 2015 - pubs.rsc.org
The peroxydisulfate anion has long been used for the preparation of hexavalent americium
(AmVI) from the normally stable AmIII valence state in mildly acidic solutions. However, there …

Bimolecular radical termination: New perspectives and insights

G Johnston‐Hall, MJ Monteiro - Journal of Polymer Science …, 2008 - Wiley Online Library
The reversible addition‐fragmentation chain transfer‐chain length dependent termination
(RAFT‐CLD‐T) method has allowed us to answer a number of fundamental questions …

[图书][B] Reactions and synthesis in surfactant systems

J Texter - 2001 - api.taylorfrancis.com
This book presents a review of extant applications of surfactant technology in chemical
synthesis as well as chemical reactions and catalysis. The applications and utilization of …

Modelling particle size distributions and secondary particle formation in emulsion polymerisation

EM Coen, RG Gilbert, BR Morrison, H Leube, S Peach - Polymer, 1998 - Elsevier
An extensive model is given for the particle size distribution (PSD), particle number, particle
size and amount of secondary nucleation in emulsion polymerisations. This incorporates …