Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Transfer of sulfur: from simple to diverse

H Liu, X Jiang - Chemistry–An Asian Journal, 2013 - Wiley Online Library
The introduction of sulfur atoms onto target molecules is an important area in organic
synthesis, in particular in the synthesis of pharmaceutical compounds, and a wide variety of …

Isothiazolinone biocides: chemistry, biological, and toxicity profiles

V Silva, C Silva, P Soares, EM Garrido, F Borges… - Molecules, 2020 - mdpi.com
The importance of isothiazole and of compounds containing the isothiazole nucleus has
been growing over the last few years. Isothiazolinones are used in cosmetic and as …

Recent advances in the chemistry of organic thiocyanates

T Castanheiro, J Suffert, M Donnard… - Chemical Society …, 2016 - pubs.rsc.org
Organic thiocyanates are important synthetic intermediates to access valuable sulfur-
containing compounds. In this review the different methods for their preparation and their …

Metal-catalyzed C–S bond formation using sulfur surrogates

N Sundaravelu, S Sangeetha, G Sekar - Organic & Biomolecular …, 2021 - pubs.rsc.org
Sulfur-containing compounds are present in a wide range of biologically important natural
products, drugs, catalysts, and ligands and they have wide applications in material …

Copper (II)‐Catalyzed Three‐Component Cascade Annulation of Diaryliodoniums, Nitriles, and Alkynes: A Regioselective Synthesis of Multiply Substituted Quinolines

Y Wang, C Chen, J Peng, M Li - Angewandte Chemie, 2013 - infona.pl
Copper(II)‐Catalyzed Three‐Component Cascade Annulation of Diaryliodoniums, Nitriles,
and Alkynes: A Regioselective Synthesis of Multiply Substituted Quinolines × Close The …

Photocatalytic C–H Thiocyanation of NH2-Enaminones and the Tunable Synthetic Routes to 2-Aminothiazoles and 2-Thiazolinones

J Zeng, JP Wan, Y Liu - The Journal of Organic Chemistry, 2022 - ACS Publications
Visible light photocatalytic reactions of NH2-enaminones and ammonium thiocyanate for
chemoselective α-C–H thiocyanation have been realized for the first time, providing a …

Transition-metal-free tandem radical thiocyanooxygenation of olefinic amides: a new route to SCN-containing heterocycles

H Yang, XH Duan, JF Zhao, LN Guo - Organic letters, 2015 - ACS Publications
A novel transition-metal-free tandem radical thiocyanooxygenation of olefinic amides with
potassium thiocyanate has been developed under mild conditions. This method allows a …

N-Thiocyanatosaccharin: A “Sweet” Electrophilic Thiocyanation Reagent and the Synthetic Applications

D Wu, J Qiu, PG Karmaker, H Yin… - The Journal of Organic …, 2018 - ACS Publications
N-Thiocyanatosaccharin (R 1) was readily prepared from the sweet additive Saccharin in
two steps with a 71% overall yield. By applying this new reagent to diverse nucleophiles …

Electrosynthesis of (E)-Vinyl Thiocyanates from Cinnamic Acids via Decarboxylative Coupling Reaction

SM Yang, TJ He, DZ Lin, JM Huang - Organic letters, 2019 - ACS Publications
Thiocyanate compounds are key intermediates in the synthesis of pharmaceuticals and
other sulfur-containing organic compounds. Herein, we first report an electrochemical …