The photophysics of photoredox catalysis: a roadmap for catalyst design
DM Arias-Rotondo, JK McCusker - Chemical Society Reviews, 2016 - pubs.rsc.org
Recently, the use of transition metal based chromophores as photo-induced single-electron
transfer reagents in synthetic organic chemistry has opened up a wealth of possibilities for …
transfer reagents in synthetic organic chemistry has opened up a wealth of possibilities for …
Electronic structure in the transition metal block and its implications for light harvesting
JK McCusker - Science, 2019 - science.org
Transition metal–based chromophores play a central role in a variety of light-enabled
chemical processes ranging from artificial solar energy conversion to photoredox catalysis …
chemical processes ranging from artificial solar energy conversion to photoredox catalysis …
Manganese(i) complexes with metal-to-ligand charge transfer luminescence and photoreactivity
Precious metal complexes with the d 6 valence electron configuration often exhibit
luminescent metal-to-ligand charge transfer (MLCT) excited states, which form the basis for …
luminescent metal-to-ligand charge transfer (MLCT) excited states, which form the basis for …
Janus-type emission from a cyclometalated iron(iii) complex
J Steube, A Kruse, OS Bokareva, T Reuter… - Nature Chemistry, 2023 - nature.com
Although iron is a dream candidate to substitute noble metals in photoactive complexes,
realization of emissive and photoactive iron compounds is demanding due to the fast …
realization of emissive and photoactive iron compounds is demanding due to the fast …
A low-spin Fe(iii) complex with 100-ps ligand-to-metal charge transfer photoluminescence
Transition-metal complexes are used as photosensitizers, in light-emitting diodes, for
biosensing and in photocatalysis. A key feature in these applications is excitation from the …
biosensing and in photocatalysis. A key feature in these applications is excitation from the …
Cobalt (III) carbene complex with an electronic excited-state structure similar to cyclometalated iridium (III) compounds
Many organometallic iridium (III) complexes have photoactive excited states with mixed
metal-to-ligand and intraligand charge transfer (MLCT/ILCT) character, which form the basis …
metal-to-ligand and intraligand charge transfer (MLCT/ILCT) character, which form the basis …
Delayed fluorescence from a zirconium(iv) photosensitizer with ligand-to-metal charge-transfer excited states
Advances in chemical control of the photophysical properties of transition-metal complexes
are revolutionizing a wide range of technologies, particularly photocatalysis and light …
are revolutionizing a wide range of technologies, particularly photocatalysis and light …
Energy transfer to Ni-amine complexes in dual catalytic, light-driven C–N cross-coupling reactions
Dual catalytic light-driven cross-coupling methodologies utilizing a Ni (II) salt with a
photocatalyst (PC) have emerged as promising methodologies to forge aryl C–N bonds …
photocatalyst (PC) have emerged as promising methodologies to forge aryl C–N bonds …
Iron(ii) coordination complexes with panchromatic absorption and nanosecond charge-transfer excited state lifetimes
Replacing current benchmark rare-element photosensitizers with ones based on abundant
and low-cost metals such as iron would help facilitate the large-scale implementation of …
and low-cost metals such as iron would help facilitate the large-scale implementation of …
Leveraging excited-state coherence for synthetic control of ultrafast dynamics
BC Paulus, SL Adelman, LL Jamula, JK McCusker - Nature, 2020 - nature.com
Abstract Design-specific control over excited-state dynamics is necessary for any application
seeking to convert light into chemical potential. Such control is especially desirable in iron …
seeking to convert light into chemical potential. Such control is especially desirable in iron …