Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …

Low-valent early transition metals are often intrinsically highly reactive as a result of their
strong propensity toward oxidation to more stable high-valent states. Harnessing these …

New catalytic strategies that leverage single-electron redox events have provided chemists
with useful tools for solving synthetic problems. In this context, Ti offers opportunities that are …

Alkyl chlorides are common functional groups in synthetic organic chemistry. However, the
engagement of unactivated alkyl chlorides, especially tertiary alkyl chlorides, in transition …

Transition‐metal‐catalyzed radical reactions are becoming increasingly important in modern
organic chemistry. They offer fascinating and unconventional ways for connecting molecular …

Reduction, please! The title reaction affords α-hydroxyketones, a common structural motif in
biologically active natural products, in good yields and high enantioselectivities at room …

We describe a combination of catalysts that allows the coupling of titanocene (III) catalysis
with photoredox catalysis. Oxidation of radical intermediates by a photoredox catalyst opens …

The development of Green Chemistry inevitably involves the development of green
reagents. In this review, we highlight that Cp2TiCl is a reagent widely used in radical and …

In the last two decades, titanocene monochloride has been postulated as a monoelectronic
transfer reagent capable of catalyzing an important variety of chemical transformations. In …

Aziridines activated by N‐acylation are opened to the higher substituted radical through
electron transfer from titanocene (III) complexes in a novel catalytic reaction. This reaction is …