An Account of chiral metal surfaces and their enantiospecific chemistry

AJ Gellman - Accounts of Materials Research, 2021 - ACS Publications
Conspectus Molecular chirality has been of scientific interest since 1848 when Pasteur
demonstrated its direct connection to the rotation of light by solutions of chiral compounds. In …

Enantiomer Adsorption in an Applied Magnetic Field: D‐and L‐Aspartic Acid on Ni (100)

M Radetic, AJ Gellman - Israel Journal of Chemistry, 2022 - Wiley Online Library
There have been several reports of the enantiospecific adsorption of chiral compounds from
solution onto ferromagnetic surfaces in applied magnetic fields. This work studies the …

Kinetics and mechanism of aspartic acid adsorption and its explosive decomposition on Cu (100)

B Karagoz, A Reinicker, AJ Gellman - Langmuir, 2019 - ACS Publications
The mechanism and kinetics of aspartic acid (Asp, HO2CCH (NH2) CH2CO2H)
decomposition on Cu (100) have been studied using X-ray photoemission spectroscopy and …

2D Ising Model for Adsorption‐induced Enantiopurification of Racemates

S Dutta, Y Yun, M Widom, AJ Gellman - ChemPhysChem, 2021 - Wiley Online Library
Mechanisms for the spontaneous transformation of achiral chemical systems into states of
enantiomeric purity have important ramifications in modern pharmacology and potential …

2D Ising model for enantiomer adsorption on achiral surfaces: L-and D-aspartic acid on Cu (111)

S Dutta, AJ Gellman - Entropy, 2022 - mdpi.com
The 2D Ising model is well-formulated to address problems in adsorption thermodynamics. It
is particularly well-suited to describing the adsorption isotherms predicting the surface …

Initiation of vacancy-mediated, surface explosion reactions: tartaric and aspartic acid on Cu Surfaces

P Kondratyuk, B Karagoz, Y Yun… - The Journal of Physical …, 2019 - ACS Publications
Surface explosion reactions have highly nonlinear reaction kinetics that exhibit
autoacceleration under isothermal conditions. These can lead to phenomena such as …

Enantiospecific equilibrium adsorption and chemistry of d‐/l‐proline mixtures on chiral and achiral Cu surfaces

S Dutta, AJ Gellman - Chirality, 2020 - Wiley Online Library
A fundamental understanding of the enantiospecific interactions between chiral adsorbates
and understanding of their interactions with chiral surfaces is key to unlocking the origins of …

Enantioselective Surface Chemistry on All Chiral Cu (𝒉kl) Surfaces: D-, L-and meso-Tartaric Acid and D-, L-Aspartic Acid

C Fernández-Cabán - 2022 - search.proquest.com
The biomolecular homochirality of living organisms and the enantiospecificity of chiral
bioactive molecules on Earth create the need for chemical processes that yield …

Surface Chemistry of Chiral Compounds on Chiral and Achiral Surfaces

M Radetic - 2021 - search.proquest.com
This works aims to expand our understanding of amino acid surface chemistry on chiral and
achiral metallic substrates. Both experimental and computational methods are employed to …

Structure Sensitivity of Enantioselective Surface Chemistry on Cu (hkl) Surfaces

B Karagoz - 2019 - search.proquest.com
The chiral surface chemistry aims to understand the origin of enantiospecific interactions
between chiral molecules and chiral surfaces. The key to understanding the origin of …