Phonon confinement and size effect in Raman spectra of ZnO nanoparticles

VI Korepanov, SY Chan, HC Hsu, H Hamaguchi - Heliyon, 2019 - cell.com
We study Raman spectra of ZnO nanoparticles of 5–12 nm size in the whole range of the first-
order phonon bands. We apply the 3D phonon confinement model (PCM) for the …

Spectroelectrochemistry of quantum dots

J Garoz‐Ruiz, JV Perales‐Rondon… - Israel Journal of …, 2019 - Wiley Online Library
Spectroelectrochemistry (SEC) is a set of techniques with many advantages in the study and
characterization of materials. Although SEC has not yet been widely used to study quantum …

Localized phonons in Raman spectra of nanoparticles and disordered media

VI Korepanov - Journal of Raman Spectroscopy, 2020 - Wiley Online Library
Several approaches may be used to link the Raman spectra to the characteristic size scale
of nanomaterials. To treat the vibrations of the nanocrystal as localized phonons is a basic …

Oxidation and strain in free-standing silicon nanocrystals

BP Falcao, JP Leitão, MR Soares, L Ricardo… - Physical Review …, 2019 - APS
The investigation of surface-induced lattice-strain effects in free-standing silicon
nanocrystals (Si NCs) is fundamental in view of the materialization of nanosilicon-based …

Raman spectroscopy of colloidal semiconductor nanocrystals

K Boldt - Nano Futures, 2022 - iopscience.iop.org
Raman spectroscopy is a powerful method that gives insight into the atomic structure and
composition of nanomaterials, but also allows to draw conclusions about their electronic …

The common and intrinsic skin electric-double-layer (EDL) and its bonding characteristics of nanostructures

Y Peng, Z Tong, Y Yang, CQ Sun - Applied Surface Science, 2021 - Elsevier
We show that nanocrystals share a common and intrinsic skin electric-double-layer (EDL).
The EDL is determined to be 2.14 regular-bond-length thick using differential phonon …

Recombination of photo-generated charge carriers in H-terminated and (photo-) oxidized silicon nanoparticles

BP Falcao, JP Leitao, L Ricardo, H Aguas… - Applied Materials …, 2021 - Elsevier
The mechanisms of recombination of photo-generated charge carriers and the origin of
luminescence in silicon nanocrystals, quantum dots or nanoparticles (Si-NPs) are essential …

Stacking driven Raman spectra change of carbon based 2D semiconductor C3N

Y Yang, W Wei, P He, S Yang, Q Yuan, G Ding… - Chinese Chemical …, 2022 - Elsevier
As a two-dimensional carbon based semiconductor, C 3 N acts as a promising material in
many application areas. However, the basic physical properties such as Raman spectrum …

Silicon Nanoparticle Films Infilled with Al2O3 Using Atomic Layer Deposition for Photosensor, Light Emission, and Photovoltaic Applications

AMP Botas, JP Leitao, BP Falcao… - ACS Applied Nano …, 2020 - ACS Publications
Solution-processed thin films of crystalline silicon nanoparticles (Si NPs) have a great
potential for a wide variety of electronic and optoelectronic applications. However, such films …

Vibrational analysis of silicon nanoparticles using simulation and decomposition of Raman spectra

ME Povarnitsyn, NS Shcheblanov, DS Ivanov… - Physical Review …, 2020 - APS
We report a classical molecular-dynamics simulation of models of silicon nanoparticles and
bulk silicon, in both the crystalline and the amorphous phase, to investigate their vibrational …