Chiral organosilanes are of great value in asymmetric synthesis, functional materials, and
medicinal chemistry. Compared with single-silyl compounds, bis (silyl) ones are …

Here, we reported a cobalt-hydride-catalyzed Markovnikov-type hydroallylation of terminal
alkynes with allylic electrophile to access valuable and branched skipped dienes (1, 4 …

Enantioselective cobalt‐catalyzed one‐pot hydrosilylation and hydroboration of terminal
alkynes has been developed employing a cobalt catalyst generated from Co (acac) 2 and …

Hydrosilylation of unsaturated carbon-carbon bonds with hydrosilanes is a very important
process to access organosilicon compounds and ranks as one of the most fundamental …

A three-component reaction for 1, 2-amino oxygenation of 1, 3-dienes has been achieved
using O-acyl hydroxylamines and carboxylic acids. The reaction occurs through copper …

Summary of main observation and conclusion A regioselective double 1, 1‐hydrosilylation of
terminal aliphatic alkynes with primary silanes catalyzed by one cobalt catalyst has been …

Mixing i‐PrI and DABCO in solvent EtCN gave two quaternary ammonium salts (QASs)
quantitatively, one of which is monocationic (QAS‐1) and the other is dicationic (QAS‐2) …

Abstract A transition‐metal‐free (5+ 1) cycloaddition of aryl‐substituted vinylcyclopropanes
(VCPs) and hydrosilanes to afford silacyclohexanes is reported. Catalytic amounts of the …

Described herein is the development of a new synthetic route to cyclic amidines from
quinolines. The borane-catalyzed 1, 4-hydrosilylation of quinoline was utilized for the …

Catalytic silicon‐carbon or silicon‐heteroatom bond‐forming hydrosilylation has become
increasingly important in synthetic chemistry, catalysis and organosilicon chemistry. Herein …