Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

TW van Deelen, C Hernández Mejía, KP de Jong - Nature Catalysis, 2019 - nature.com
Metal nanoparticles stabilized on a support material catalyse many major industrial
reactions. Metal-support interactions in these nanomaterials can have a substantial …

Review of the decomposition of ammonia to generate hydrogen

I Lucentini, X Garcia, X Vendrell… - Industrial & Engineering …, 2021 - ACS Publications
Because of the problems associated with the generation and storage of hydrogen in
portable applications, the use of ammonia has been proposed for on-site production of …

Recent advances in hydrodeoxygenation of biomass-derived oxygenates over heterogeneous catalysts

S Kim, EE Kwon, YT Kim, S Jung, HJ Kim… - Green …, 2019 - pubs.rsc.org
Hydrodeoxygenation (HDO) using heterogeneous catalysts has received considerable
attention as a way of converting biomass-derived oxygenates into renewable fuels and …

Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts

N Daelman, M Capdevila-Cortada, N López - Nature materials, 2019 - nature.com
The catalytic activity of metals supported on oxides depends on their charge and oxidation
state. Yet, the determination of the degree of charge transfer at the interface remains elusive …

Ceria catalysts at nanoscale: how do crystal shapes shape catalysis?

A Trovarelli, J Llorca - ACS catalysis, 2017 - ACS Publications
Engineering the shape and size of catalyst particles and the interface between different
components of heterogeneous catalysts at the nanometer level can radically alter their …

Bifunctional catalysts for upgrading of biomass-derived oxygenates: a review

AM Robinson, JE Hensley, JW Medlin - ACS catalysis, 2016 - ACS Publications
Deoxygenation is an important reaction in the conversion of biomass-derived oxygenates to
fuels and chemicals. A key route for biomass refining involves the production of pyrolysis oil …

Structural transformations of solid electrocatalysts and photocatalysts

L Liu, A Corma - Nature Reviews Chemistry, 2021 - nature.com
Heterogeneous catalysts often undergo structural transformations when they operate under
thermal reaction conditions. These transformations are reflected in their evolving catalytic …

Activity enhancement of cobalt catalysts by tuning metal-support interactions

C Hernández Mejía, TW van Deelen… - Nature …, 2018 - nature.com
Interactions between metal nanoparticles and support materials can strongly influence the
performance of catalysts. In particular, reducible oxidic supports can form suboxides that can …

Atomic‐Scale Structure Dynamics of Nanocrystals Revealed By In Situ and Environmental Transmission Electron Microscopy

H Zhao, Y Zhu, H Ye, Y He, H Li, Y Sun… - Advanced …, 2023 - Wiley Online Library
Nanocrystals are of great importance in material sciences and industry. Engineering
nanocrystals with desired structures and properties is no doubt one of the most important …