Electrochemistry of metal-metal bonded diruthenium complexes

E Van Caemelbecke, T Phan, WR Osterloh… - Coordination Chemistry …, 2021 - Elsevier
This review summarizes the known electrochemistry of metal-metal bonded diruthenium
complexes containing an air-stable Ru 2 4+, Ru 2 5+ or Ru 2 6+ core or an in-situ generated …

The use of amidinate ligands in paddlewheel diruthenium chemistry

M Cortijo, R Gonzalez-Prieto, S Herrero… - Coordination Chemistry …, 2019 - Elsevier
The amidinate anions have been widely used in the formation of dinuclear complexes with
paddlewheel structure. The higher donor character of this type of ligands, compared to …

Supramolecular assemblies of multi-nuclear transition metal complexes: Synthesis and redox properties

S Tanaka, H Tsurugi, K Mashima - Coordination Chemistry Reviews, 2014 - Elsevier
The synthetic features of supramolecular assemblies comprised of multi-nuclear transition
metal complexes were reviewed by classification of the reaction patterns:(1) substitution …

Triphenylbismuth (v) di [(iso) nicotinates]–transmetallation agents or divergent organometalloligands? First organobismuth (v)-based silver (i) coordination polymers

AB Kiran, T Mocanu, A Pöllnitz, S Shova… - Dalton …, 2018 - pubs.rsc.org
The reaction of Ph3BiCl2 with alkali salts of isonicotinic and nicotinic acids afforded Ph3Bi
[O (O) CC5H4N-4] 2 (1) and Ph3Bi [O (O) CC5H4N-3] 2 (2), respectively, which were …

Capturing the missing [AgF 2]− anion within an Ru 2 (iii/iii) dimeric dumbbell complex

AR Corcos, JF Berry - Dalton Transactions, 2016 - pubs.rsc.org
The complex {[Ru2 (ap) 4] 2 [AgF2]}[BF4] 3 ({2}[BF4] 3, ap= 2-anilinopyridine), containing the
[AgF2]− anion ligated to two [Ru2] 6+ cores, is prepared, characterized, and compared to …

Coordination polymers and supramolecular solid-state architectures constructed from an organometallic tecton, bis (4-pyridyl) mercury

T Mocanu, L Kiss, A Sava, S Shova, C Silvestru… - Polyhedron, 2019 - Elsevier
Four new 1-D coordination polymers have been assembled using bis (4-pyridyl) mercury (py
2 Hg) as spacer: 1∞[Mn (hfac) 2 (py 2 Hg)] 1, 1∞[Zn (CH 3 COO) 2 (py 2 Hg)]∙ 2H 2 O 2; …

Mn8 Cluster with Ferrocene-1,1′-Dicarboxylate Ligation: Single-Molecule Magnetism with Multiple External Redox Centers

A Masello, KA Abboud, W Wernsdorfer… - Inorganic …, 2013 - ACS Publications
The syntheses, structures, and magnetic properties are reported of a new Mn8 cluster
obtained from the reaction of ferrocene-1, 1′-dicarboxylic acid (fdcH2) with [Mn12O12 …

Structural, magnetic, and 1H NMR spectral study on lantern-type cis-and trans-diruthenium (II, III) complexes with two formamidinato and two acetato bridges

T Ikeue, Y Kimura, K Karino, M Iida, T Yamaji… - Inorganic Chemistry …, 2013 - Elsevier
Lantern-type dinuclear complexes, cis-[Ru2 (4-Me-pf) 2 (O2CMe) 2Cl] and trans-[Ru2 (2, 6-
Et2-pf) 2 (O2CMe) 2Cl](4-Me-pf−= N, N′-bis (4-methylphenyl) formamidinate ion and 2, 6 …

Experimental and theoretical study of dimer-of-dimers-type tetrarhodium (ii) complexes bridged by 1, 4-benzenedicarboxylate linkers

Y Kataoka, K Arakawa, H Ueda, N Yano… - Dalton …, 2018 - pubs.rsc.org
Two dimer-of-dimers-type tetrarhodium complexes,[Rh4 (piv) 6 (BDC)]([1]; piv= pivalate) and
[Rh4 (piv) 6 (F4BDC)]([2]), in which two paddlewheel-type dirhodium units are linked by 1, 4 …

Diosmium carbonyl sawhorse complexes containing a ferrocenedicarboxylato ligand

DM Marolf, JE Johnstone, HA Touchton… - Journal of …, 2022 - Taylor & Francis
In an attempt to prepare a supramolecular assembly consisting of two, three, or four
diosmium carbonyl sawhorse units linked together by dicarboxylato ligands, the reaction of …